Diverse reactivity of an iron-aluminium complex with substituted pyridines.
Chem Commun (Camb)
; 58(77): 10849-10852, 2022 Sep 27.
Article
em En
| MEDLINE
| ID: mdl-36073319
ABSTRACT
The reaction of an Fe-Al complex with an array of substituted pyridines is reported. Depending on the substitution pattern of the substrate site-selective sp2 or sp3 C-H bond activation is observed. A series of reaction products are observed based on (i) C-Al bond formation, (ii) C-C bond formation by nucleophilic addition or (iii) deprotonation of the ß-diketiminate ligand. A divergent set of mechanisms involving a common intermediate is proposed.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Alumínio
/
Ferro
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
Reino Unido