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Two-photon, red light uncaging of alkyl radicals from organorhodium(III) phthalocyanine complexes.
Murata, Kei; Saibe, Yuki; Uchida, Mayu; Aono, Mizuki; Misawa, Ryuji; Ikeuchi, Yoshiho; Ishii, Kazuyuki.
Afiliação
  • Murata K; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Saibe Y; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Uchida M; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Aono M; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Misawa R; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Ikeuchi Y; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
  • Ishii K; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan. murata-k@iis.u-tokyo.ac.jp.
Chem Commun (Camb) ; 58(80): 11280-11283, 2022 Oct 06.
Article em En | MEDLINE | ID: mdl-36124703
ABSTRACT
A stepwise two-photon, red light excitation of organorhodium(III) phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the photouncaging reaction and the photochemical generation of reactive oxygen species were indicated to induce the cell deaths.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Indóis / Luz Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Japão
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Indóis / Luz Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Japão