A Polyfluoroalkyl-Containing Non-fullerene Acceptor Enables Self-Stratification in Organic Solar Cells.
Angew Chem Int Ed Engl
; 62(1): e202213869, 2023 Jan 02.
Article
em En
| MEDLINE
| ID: mdl-36333961
ABSTRACT
The elaborate control of the vertical phase distribution within an active layer is critical to ensuring the high performance of organic solar cells (OSCs), but is challenging. Herein, a self-stratification active layer is realised by adding a novel polyfluoroalkyl-containing non-fullerene small-molecule acceptor (NFSMA), EH-C8 F17 , as the guest into PM6BTP-eC9 blend. A favourable vertical morphology was obtained with an upper acceptor-enriched thin layer and a lower undisturbed bulk heterojunction layer. Consequently, a power conversion efficiency of 18.03 % was achieved, higher than the efficiency of 17.40 % for the device without EH-C8 F17 . Additionally, benefiting from the improved charge transport and collection realised by this self-stratification strategy, the OSC with a thickness of 350â
nm had an impressive PCE of 16.89 %. The results of the study indicate that polyfluoroalkyl-containing NFSMA-assisted self-stratification within the active layer is effective for realising an ideal morphology for high-performance OSCs.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Prognostic_studies
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2023
Tipo de documento:
Article