Study on adsorption and recovery utilization of phosphorus using alkali melting-hydrothermal treated oil-based drilling cutting ash.

Oil-based drill cutting ash (OBDCA) was treated by alkali melting-hydrothermal method and used as novel adsorbent (AM-HT-OBDCA) for the recovery of phosphorus (P) in water body. The experiment parameter for preparation of AM-HT-OBDCA was optimized, including alkali melting ratio (MOBDCA: MNaOH), alkali melting temperature and hydrothermal temperature. The adsorption process of phosphorus on AM-HT-OBDCA was fit well with the pseudo-second-order model and the Langmuir model. The calculated theoretic adsorption capacity of phosphorus on AM-HT-OBDCA was 62.9 mg/g. The adsorption behavior was spontaneous and endothermic. The effect of pH value and interfering ions on the adsorption of phosphorus in AM-HT-OBDCA was investigated. The main existing form of adsorbed phosphorus on AM-HT-OBDCA was sodium hydroxide extraction form phosphorus (NaOH-P), including iron form phosphorus (Fe-P) and aluminum form phosphorus (Al-P). Precipitation and ligand exchange were the main mechanisms of phosphorus adsorption on AM-HT-OBDCA. The AM-HT-OBDCA used for phosphorus adsorption (AM-HT-OBDCA-P) could be further utilized as fertilizer to promote plant growth. The results of this study provide fundamental data and evaluation support for resource utilization of OBDCA. These results will also provide a reference for the adsorption and recovery utilization of phosphorus using solid waste-based adsorbent.