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Rational design of Lewis base molecules for stable and efficient inverted perovskite solar cells.
Li, Chongwen; Wang, Xiaoming; Bi, Enbing; Jiang, Fangyuan; Park, So Min; Li, You; Chen, Lei; Wang, Zaiwei; Zeng, Lewei; Chen, Hao; Liu, Yanjiang; Grice, Corey R; Abudulimu, Abasi; Chung, Jaehoon; Xian, Yeming; Zhu, Tao; Lai, Huagui; Chen, Bin; Ellingson, Randy J; Fu, Fan; Ginger, David S; Song, Zhaoning; Sargent, Edward H; Yan, Yanfa.
Afiliação
  • Li C; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Wang X; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Bi E; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Jiang F; Department of Chemistry, University of Washington, Seattle, WA 98195, USA.
  • Park SM; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Li Y; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Chen L; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Wang Z; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Zeng L; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Chen H; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Liu Y; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Grice CR; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Abudulimu A; Center for Materials and Sensors Characterization, The University of Toledo, Toledo, OH 43606, USA.
  • Chung J; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Xian Y; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Zhu T; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Lai H; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Chen B; Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, Dübendorf 8600, Switzerland.
  • Ellingson RJ; The Edward S. Rogers Department of Electrical and Computer Engineering, University of Toronto, Toronto, ON M5S 3G4, Canada.
  • Fu F; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
  • Ginger DS; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
  • Song Z; Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, Dübendorf 8600, Switzerland.
  • Sargent EH; Department of Chemistry, University of Washington, Seattle, WA 98195, USA.
  • Yan Y; Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, OH 43606, USA.
Science ; 379(6633): 690-694, 2023 Feb 17.
Article em En | MEDLINE | ID: mdl-36795809
ABSTRACT
Lewis base molecules that bind undercoordinated lead atoms at interfaces and grain boundaries (GBs) are known to enhance the durability of metal halide perovskite solar cells (PSCs). Using density functional theory calculations, we found that phosphine-containing molecules have the strongest binding energy among members of a library of Lewis base molecules studied herein. Experimentally, we found that the best inverted PSC treated with 1,3-bis(diphenylphosphino)propane (DPPP), a diphosphine Lewis base that passivates, binds, and bridges interfaces and GBs, retained a power conversion efficiency (PCE) slightly higher than its initial PCE of ~23% after continuous operation under simulated AM1.5 illumination at the maximum power point and at ~40°C for >3500 hours. DPPP-treated devices showed a similar increase in PCE after being kept under open-circuit conditions at 85°C for >1500 hours.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Science Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Estados Unidos
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XML
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Science Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Estados Unidos