Asymmetric arene hydrogenation: towards sustainability and application.
Chem Soc Rev
; 52(15): 4996-5012, 2023 Jul 31.
Article
em En
| MEDLINE
| ID: mdl-37427715
ABSTRACT
(Hetero)aromatic compounds are vastly available and easy to functionalise building blocks in the chemical industry. Asymmetric arene hydrogenation enables direct access to complex three-dimensional scaffolds with (multiple) defined stereocentres in a single catalytic process and, by this, the rapid installation of molecular complexity. The potential usage of hydrogen from renewable sources and perfect atom economy bears the potential for sustainable and broadly applicable transformations to valuable products. The aim of this review is to present the state-of-the-art in transition-metal catalysed asymmetric hydrogenation of (hetero)arenes, to highlight recent advances and important trends and to provide a broad overview for the reader.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Soc Rev
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Alemanha