Directional Assembly of Large-Area Silica Nanorod Film Using the Electric-Field-Assisted Capillary Channel Method.

ABSTRACT

The self-assembly of colloidal particles, especially colloidal particles with anisotropic geometry, is important for applications in the construction of many functional materials. Compared with the self-assembly of colloidal particles with isotropic geometries, not only does the geometric orientation among neighboring anisotropic particles need to be considered for the reduction of Gibbs free energy, the orientations of the particles are best to be externally influenced. Because of this, the preparation of assembled nanorod arrays with uniform alignment across a large area is still a significant challenge. In this work, an electric-field-assisted capillary channel method is reported, using an external electric field to influence the orientation of silica nanorods or FeOOH ellipsoids during assembly. By application of an external electric field, the alignment of the nanorods is effectively controlled. The capillary channel method provides continuous replenishment of a colloidal solution containing nanorods or spheres for assembly of large-area films. The area of the formed films was influenced by the assembly temperature, channel width, colloidal solution concentration, and solvent surface tension. The competition between the thermal Brownian motion and torque generated by the external electric field impacted the nanorod array quality in the film. While increasing the intensity of the electric field improved nanorod alignment, applying a potential greater than 6 V also produced a heating effect, negatively affecting the quality of the nanorod arrays. The nematic order parameter S which characterizes the degree of alignment of FeOOH ellipsoids with smaller length is significantly lower than the one for silica nanorods due to the higher critical field strength and the increased susceptibility to the effects of thermal motion. The assembly of silica nanorods at 35 °C under an effective potential of 4-6 V provides a compromise between achieving uniform nanorod orientation and maximizing the coverage area of the colloidal film.