Synthesis of Hybrid Porphyrin(2.1.2.1)s and Their Complexation.

Dong, Yuting; Morimoto, Hirofumi; Lv, Xiaojuan; Mo, Xuehuan; Chen, Feng; Wu, Fan; Aratani, Naoki; Qiu, Fengxian; Xue, Songlin

Dong, Yuting; Morimoto, Hirofumi; Lv, Xiaojuan; Mo, Xuehuan; Chen, Feng; Wu, Fan; Aratani, Naoki; Qiu, Fengxian; Xue, Songlin.

Afiliação

Dong Y; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.
Morimoto H; Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama-cho, Ikoma ,Nara 630-0192, Japan.
Lv X; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.
Mo X; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.
Chen F; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.
Wu F; State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.
Aratani N; Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama-cho, Ikoma ,Nara 630-0192, Japan.
Qiu F; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.
Xue S; School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China.

J Org Chem ; 89(3): 1626-1632, 2024 Feb 02.

Article em En | MEDLINE | ID: mdl-38252075

ABSTRACT

ABSTRACT

Novel hybrid porphyrin(2.1.2.1)s and their boron and copper complexes were synthesized using the "toy bricks" synthetic method. Crystal data, frontier molecular orbital calculations, and electrostatic potential surface maps reveal that hybridization in the porphyrin(2.1.2.1) donor-acceptor unit controls the selective coordination of BF2.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem / J. org. chem / Journal of organic chemistry Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China

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