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Methyl-Symmetrically Substituted Poly(3,4-Dimethylthiophene) as Cathode for Aluminum Ion Batteries.
Li, Sihang; Wang, Juan; Zhou, Min; Jiang, Kai; Wang, Kangli.
Afiliação
  • Li S; School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.
  • Wang J; School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.
  • Zhou M; School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.
  • Jiang K; State Key Laboratory of Advanced Electromagnetic Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.
  • Wang K; Engineering Research Center of Power Safety and Efficiency, Ministry of Education, Wuhan, Hubei, 430074, China.
Chemistry ; 30(18): e202303892, 2024 Mar 25.
Article em En | MEDLINE | ID: mdl-38279783
ABSTRACT
The aggravation of energy problems and the scarcity of lithium resources have forced us to look for new energy storage systems. Aluminum ion batteries, as a promising energy storage system, have the advantages of environmental friendliness and abundant aluminum resources, and have the potential for application in large-scale energy storage and personal portable electronic devices. To solve the stability problem of aluminum ion batteries during cycling for large-scale energy storage needs, we report a polythiophene-based conductive polymer, poly(3,4-dimethylthiophene) (PDMT), as a high performance cathode material for aluminum ion batteries. By introducing two methyl groups on the thiophene ring, we successfully adjust the local charge density of the heterocyclic thiophene, thus changing the electron delocalization characteristics, and improving the electrochemical reaction activity of the polythiophene (PTH) material as a redox electrode material. This also maintains the symmetry and regularity of the polymer structure, giving the material better cycling stability. The discharge specific capacity reaches 110 mAh g-1 at a current density of 200 mA g-1, far exceeding conventional PTH cathodes (~70 mAh g-1), and the capacity retention rate is 92.7 % after 1000 cycles. It also shows excellent rate performance due to the flexible structure of the conductive polymer.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China