Traffic-related metals in urban snow cover: A review of the literature data and the feasibility of filling gaps by field data collection.

ABSTRACT

A literature search on traffic related metals in polluted urban snow revealed a significant volume of references representing a substantive knowledge base. The frequently studied metals in urban snow included Zn, Cu, Pb, Cd and Ni. However, comparing metal concentrations across studies proves to be a complex effort due to the variations in site-specific factors among studies, such as traffic intensity, pavement conditions, hydrometeorological conditions, and research method aspects, such as sampling equipment and frequency, and laboratory analytical methods. The literature review indicated that among the commonly studied metals, Zn and Cu indicated potential environmental concerns, and that there was a lack of data on the occurrence and accumulation in snow of antimony (Sb), tungsten (W), and platinum group elements (PGEs). To partly mitigate this knowledge gap, a field study of these elements was carried out by sampling urban roadside snow at six locations with various land use and traffic intensities, focusing on accumulation of these elements in snowbanks along roadways. The results indicated that traffic related activities are the sources of PGEs, W and Sb in roadside snowbanks, as the concentrations of these metals increased with increasing traffic intensity. The mean concentrations of the studied metals followed this descending order W (0.4 (Reporting limit-RL)-987 µg/l) > Sb (0.1 RL-33.2 µg/l) > Pd (0.02 (RL)-0.506 µg/l) > Rh (0.02 (RL)-0.053 µg/l). In laboratory melted snow, both W and Sb were mostly in the particulate-bound phase, with <25 % in the dissolved phase. For sites with metal concentrations above the detection limit, the regression analysis indicated linear trends in unit area deposition rates of W with time (snow age), described by R2 = 0.94.