TEMPO/O<sub>2</sub> Synergistically Mediated BiBrO-Photocatalyzed Decarboxylative Phosphorylation of N-Arylglycines.

Ouyang, Wen-Tao; Ji, Hong-Tao; Liu, Yuan-Yuan; Li, Ting; Jiang, Yan-Fang; Lu, Yu-Han; Jiang, Jun; He, Wei-Min

TEMPO/O₂ Synergistically Mediated BiBrO-Photocatalyzed Decarboxylative Phosphorylation of N-Arylglycines.

Ouyang, Wen-Tao; Ji, Hong-Tao; Liu, Yuan-Yuan; Li, Ting; Jiang, Yan-Fang; Lu, Yu-Han; Jiang, Jun; He, Wei-Min.

Afiliação

Ouyang WT; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Ji HT; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Liu YY; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Li T; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Jiang YF; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Lu YH; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
Jiang J; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.
He WM; School of Chemistry and Chemical Engineering, University of South, China, Hengyang, 421001, China.

Chemistry ; 30(41): e202304234, 2024 Jul 19.

Article em En | MEDLINE | ID: mdl-38644695

ABSTRACT

ABSTRACT

With both TEMPO and O2 (in air) as the homogeneous redox mediators, BiBrO as the heterogeneous semiconductor photocatalyst, the first example of semi-heterogeneous photocatalytic decarboxylative phosphorylation of N-arylglycines with diarylphosphine oxides was established. A series of α-amino phosphinoxides were efficiently synthesized.

Palavras-chave

N-arylglycines; diarylphosphine oxide; photocatalysis; redox mediator; semi-heterogeneous

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China

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