A simple and precise methodology to determine particulate matter mass in atmospheric filters; validation and application cases.

In the past decades, particulate matter (PM) measurements have been used extensively in atmospheric sciences, as it allows studying the evolution of tracers for different atmospheric processes and the effects of atmospheric pollution on human health. However, measuring PM mass requires a constant control of the laboratory conditions due to its capacity to absorb humidity. For this reason, this study was focused on developing a novel, simple and precise methodology to determine the corrections of the filter mass due to humidity changes. The control and corrections are possible using a "control filter", which is always adapted to the environmental conditions of the laboratory. To check the consistency of this method, it was proved that the mass of any problem filter and that of the control filter behave in a very similar way. This allows quantifying the mass changes of any problem filter by using the control filter, where the problem filters and the control filter must have the same chemical composition and dimensions. To validate this methodology, a comparison was made between the methodology proposed in this study (Method-1) and the one proposed by the EPA (Method-2), which is generally applied. The particulate matter mass (m) was obtained for a problem filter for different weights, achieving similar values using both methods. However, Method-1 still provided reliable mass measurements for relative humidities very different from 50%, even as low as 18%. It was also proved that the adsorption or loss of water by the particulate matter can be neglected, since m is much smaller than the blank filter mass. Method-1 was also employed in several samplings carried out using three PM10 samplers to determine contaminants, such as 7Be and 210Pb, obtaining a good agreement between all particulate masses and activities measured by the three samplers for all samplings.

Assessment of metal(loid) and natural radionuclide pollution in surface sediments of an estuary affected by mining and phosphogypsum releases.

The prolonged impact over the Tinto River estuary by both the significant pollution by acid mine drainage (AMD) affecting this river and the polluted releases from phosphogypsum (PG) piles has led to the severe environmental degradation of this ecosystem. The aim of this work was to assess the current environmental quality of the Tinto River estuary through the study of the spatial distribution of metal(loid)s and natural radionuclides in the surface sediments from the channel edge. The sediments contain mean concentrations 5-20 times higher than the background values for pollutants such as Zn, As, Cu, Pb, or U, and up to two orders of magnitude higher for P. The studied sediments are heavily polluted by toxic heavy metals and metalloids (Pb, Zn, Cu, and As) according to the US EPA guidelines. Most of the analyzed sediment samples are also strongly polluted by long-lived natural radionuclides, mainly U-isotopes and 210Pb with concentrations up to one order of magnitude higher than unpolluted sediments, mostly due to the contribution by the PG leachates. The enrichment factors (EF) were extremely high (EF > 50) for As and very severe enrichment (25 ≤ EF < 50) for P, Cd, Zn, Cu, and Pb.

Assessment of the mobility of potentially toxic trace elements (PTEs) and radionuclides released in soils stabilized with mixtures of bentonite-lime-phosphogypsum.

Phosphogypsum (PG) is a solid by-product of the phosphate industry, rich in contaminants and produced in large quantities. Raw materials and stabilized specimens, consisting of bentonite-lime-PG mixtures, were characterized by mineralogical, microstructural, chemical, alpha-particle, and gamma-ray spectrometry analysis before hydration and after hardening. Compressive strength and leaching tests were performed on hardened specimens. The physicochemical parameters and chemical composition of leachates from raw materials and hardened specimens were determined. PG contains high concentrations of natural radionuclides, specially from U series. Uranium-238 activities are double in PG than the worldwide average for soil values. The mobility of PTEs from PG is Cd (2.43%), Zn (2.36%), Ni (2.07%), Cu (1.04%), Pb (0.25%), and As (0.21%). Cadmium is the cation most easily released by PG in water with a concentration 0.0316 mg kg-1. When PG is added to bentonite-lime mixture, cadmium is no longer released. The radionuclide 238,234U and 210Po predominates in the leachates of PG. However, the activity of 210Po becomes negligible in the leachates of bentonite-lime-PG mixtures. The addition of PG to bentonite-lime mixtures facilitates the trapping of trace elements (PTEs) and radionuclides, providing potential applications for PG as road embankments and fill coatings.