RESUMEN
Oil-in-water emulsions are routinely used in subsurface remediation. In these applications, high oil loadings present a challenge to remedial design as mechanistic insights into transport and retention of concentrated emulsions is limited. Column experiments were designed to examine emulsion transport and retention over a range of input concentrations (1.3-23% wt). Droplet breakthrough and retention data from low concentration experiments were successfully described by existing particle transport models. These models, however, failed to capture droplet transport in more concentrated systems. At high oil fraction, breakthrough curves exhibited an early fall at the end of the emulsion pulse and extending tailing. Irrespective of input concentration, all retention profiles displayed hyper-exponential behavior. Here, we extended existing model formulations to include the additional mixing processes occurring when at high oil concentrations-with focus on the influence of deposited mass and viscous instabilities. The resulting model was parametrized with low concentration data and can successfully predict concentrated emulsion transport and retention. The role of retained mass and viscous instabilities on mixing conditions can also be applied more broadly to systems with temporal or spatially variant water saturation or when viscosity contrasts exist between fluids.
Asunto(s)
Agua , Emulsiones , Tamaño de la Partícula , Porosidad , ViscosidadRESUMEN
Cyanobacterial harmful algal blooms (CyanoHABs) have serious adverse effects on human and environmental health. Herein, we developed a modeling framework that predicts the effect of climate change on cyanobacteria concentrations in large reservoirs in the contiguous U.S. The framework, which uses climate change projections from five global circulation models, two greenhouse gas emission scenarios, and two cyanobacterial growth scenarios, is unique in coupling climate projections with a hydrologic/water quality network model of the contiguous United States. Thus, it generates both regional and nationwide projections useful as a screening-level assessment of climate impacts on CyanoHAB prevalence as well as potential lost recreation days and associated economic value. Our projections indicate that CyanoHAB concentrations are likely to increase primarily due to water temperature increases tempered by increased nutrient levels resulting from changing demographics and climatic impacts on hydrology that drive nutrient transport. The combination of these factors results in the mean number of days of CyanoHAB occurrence ranging from about 7 days per year per waterbody under current conditions, to 16-23 days in 2050 and 18-39 days in 2090. From a regional perspective, we find the largest increases in CyanoHAB occurrence in the Northeast U.S., while the greatest impacts to recreation, in terms of costs, are in the Southeast.
Asunto(s)
Cambio Climático , Floraciones de Algas Nocivas , Cianobacterias , Agua Dulce , Humanos , Estados Unidos , Calidad del AguaRESUMEN
As human populations increase and land-use intensifies, toxic and unsightly nuisance blooms of algae are becoming larger and more frequent in freshwater lakes. In most cases, the blooms are predominantly blue-green algae (Cyanobacteria), which are favored by low ratios of nitrogen to phosphorus. In the past half century, aquatic scientists have devoted much effort to understanding the causes of such blooms and how they can be prevented or reduced. Here we review the evidence, finding that numerous long-term studies of lake ecosystems in Europe and North America show that controlling algal blooms and other symptoms of eutrophication depends on reducing inputs of a single nutrient: phosphorus. In contrast, small-scale experiments of short duration, where nutrients are added rather than removed, often give spurious and confusing results that bear little relevance to solving the problem of cyanobacteria blooms in lakes.
Asunto(s)
Lagos , Fósforo , Cianobacterias , Eutrofización , NitrógenoRESUMEN
Public health has always been, and remains, an interdisciplinary field, and engineering was closely aligned with public health for many years. Indeed, the branch of engineering that has been known at various times as sanitary engineering, public health engineering, or environmental engineering was integral to the emergence of public health as a distinct discipline. However, in the United States (U.S.) during the 20th century, the academic preparation and practice of this branch of engineering became largely separated from public health. Various factors contributed to this separation, including an evolution in leadership roles within public health; increasing specialization within public health; and the emerging environmental movement, which led to the creation of the U.S. Environmental Protection Agency (EPA), with its emphasis on the natural environment. In this paper, we consider these factors in turn. We also present a case study example of public health engineering in current practice in the U.S. that has had large-scale positive health impacts through improving water and sanitation services in Native American and Alaska Native communities. We also consider briefly how to educate engineers to work in public health in the modern world, and the benefits and challenges associated with that process. We close by discussing the global implications of public health engineering and the need to re-integrate engineering into public health practice and strengthen the connection between the two fields.
Asunto(s)
Ingeniería/historia , Ingeniería/estadística & datos numéricos , Salud Pública/historia , Salud Pública/estadística & datos numéricos , Saneamiento/historia , Abastecimiento de Agua/historia , Historia del Siglo XX , Humanos , Indígenas Norteamericanos , Ingeniería Sanitaria/historia , Ingeniería Sanitaria/métodos , Estados UnidosRESUMEN
The PhATE (Pharmaceutical Assessment and Transport Evaluation) model presented in this paper was developed as a tool to estimate concentrations of active pharmaceutical ingredients (APIs) in U.S. surface waters that result from patient use (or consumption) of medicines. PhATE uses a mass balance approach to model predicted environmental concentrations (PECs) in 11 watersheds selected to be representative of most hydrologic regions of the United States. The model divides rivers into discrete segments. It estimates the mass of API that enters a segment from upstream or from publicly owned treatment works (POTW) and is subsequently lost from the segment via in-stream loss mechanisms or flow diversions (i.e., man-made withdrawals). POTW discharge loads are estimated based on the population served, the API use per capita, the potential loss of the compound associated with human use (e.g., metabolism), and the portion of the API mass removed in the POTW. Simulations using three surrogate compounds showthat PECs generated by PhATE are generally within an order of magnitude of measured concentrations and that the cumulative probability distribution of PECs for all watersheds included in PhATE is consistent with the nationwide distribution of measured concentrations of the surrogate compounds. Model simulations for 11 APIs yielded four categories of results. (1) PECs fit measured data for two compounds. (2) PECs are below analytical method detection limits and thus are consistent with measured data for three compounds. (3) PECs are higher than (i.e., not consistent with) measured data for three compounds. However, this may be the consequence of as yet unidentified depletion mechanisms. (4) PECs are several orders of magnitude below some measured data but consistentwith most measured data forthree compounds. For the fourth category, closer examination of sampling locations suggests that the field-measured concentrations for these compounds do not accurately reflect human use. Overall, these results demonstrate that PhATE may be used to predict screening-level concentrations of APIs and related compounds in the environment as well as to evaluate the suitability of existing fate information for an API.