Heterogeneous MoS2 Nanosheets on Porous TiO2 Nanofibers toward Fast and Reversible Sodium-Ion Storage.

2D layered molybdenum disulfide (MoS2) has garnered considerable attention as an attractive electrode material in sodium-ion batteries (SIBs), but sluggish mass transfer kinetic and capacity fading make it suffer from inferior cycle capability. Herein, hierarchical MoS2 nanosheets decorated porous TiO2 nanofibers (MoS2 NSs@TiO2 NFs) with rich oxygen vacancies are engineered by microemulsion electrospinning method and subsequent hydrothermal/heat treatment. The MoS2 NSs@TiO2 NFs improves ion/electron transport kinetic and long-term cycling performance through distinctive porous structure and heterogeneous component. Consequently, the electrode exhibits excellent long-term Na storage capacity (298.4 mAh g-1 at 5 A g-1 over 1100 cycles and 235.6 mAh g-1 at 10 A g-1 over 7200 cycles). Employing Na3V2(PO4)3 as cathode, the full cell maintains a desirable capacity of 269.6 mAh g-1 over 700 cycles at 1.0 A g-1. The stepwise intercalation-conversion and insertion/extraction endows outstanding Na+ storage performance, which yields valuable insight into the advancement of fast-charging and long-cycle life SIBs anode materials.

Boosting Chemoselective Hydrogenation of Nitroaromatic via Synergy of Hydrogen Spillover and Preferential Adsorption on Magnetically Recoverable Pt@Fe2 O3.

It is highly desired but challenging to design high performance catalyst for selective hydrogenation of nitro compounds into amino compounds. Herein, a boosting chemoselective hydrogenation strategy on Pt@Fe2 O3 is proposed with gradient oxygen vacancy by synergy of hydrogen spillover and preferential adsorption. Experimental and theoretical investigations reveal that the nitro is preferentially adsorbed onto oxygen vacancy of Pt@Fe2 O3 , meanwhile, the H2 dissociated on Pt nanoparticles and then spillover to approach the nitro for selective hydrogenation (>99% conversion of 4-nitrostyrene, > 99% selectivity of 4-aminostyrene, TOF of 2351 h-1 ). Moreover, the iron oxide support endows the catalyst magnetic retrievability. This high activity, selectivity, and easy recovery strategy provide a promising avenue for selective hydrogenation catalysis of various nitroaromatic.

Placental Therapeutic Targets and Nanodelivery Systems.

Pregnancy complications affect millions of women each year. Some of these diseases have high morbidity and mortality such as preeclampsia. At present, there is no safe and effective treatment for pregnancy complications, so it is still a difficult clinical problem. As many pregnancy complications are closely related to placental dysplasia, placenta-specific therapy, as an important method, is expected to be a safe, effective, and specific therapeutic strategy. This review explains in detail the placenta physiological structure, characteristics, and action mechanism of some biomolecules and signaling pathways that play roles in normal development and disorders of the development of the placenta, and how to use these biomolecules as therapeutic targets when the placenta disorder causes disease, combining the latest progress in the field of nanodelivery systems, so as to lay a foundation for the development of placenta-specific therapy of pregnancy complications.

Small-Diameter Tube Wall Damage-Detection Method Based on TE01 Mode Microwave.

Accidents occur frequently in urban gas pipelines, and pipeline damage detection is an important means of ensuring pipeline safety. Aiming at the problem that the small diameter pipeline is difficult to detect, this paper proposes a detection method for the inner wall damage of a small-diameter pipeline based on the TE01 mode microwave and uses the TE01 mode to detect the inner wall damage of the pipeline by the terminal short-circuit reflection method. By analyzing the transition of microwave propagation mode at the defect, based on the Maxwell equation and the field distribution equation of the TE01 mode microwave in the pipe and the pipe wall current equation, the microwave reflection coefficient at the defect is established when the microwave distortion modes at the defect are TE and TM modes. A small-diameter pipeline simulation model is established, and the influence of the electric field, magnetic field, wall current distribution, and reflected wave reflection coefficient in the pipeline when inner wall defects of different widths are analyzed using the finite integral theory during microwave detection of the TE01 mode. An experimental platform for the microwave detection of small-diameter pipes was built to detect defects on the inner walls of pipes with different widths. The results show that the inner wall defect causes the electric field, magnetic field, current propagation period, and energy distribution of the TE01 mode microwave propagated in the pipe to be distorted, and the microwave reflection coefficient and return loss exhibit a significant frequency shift with the change in the defect width. The experimental and simulation results had a good consistency.

Propagation Characteristics of Magnetic Tomography Method Detection Signals of Oil and Gas Pipelines Based on Boundary Conditions.

The magnetic tomography method (MTM) is a non-contact external inspection method for detecting metal magnetic memory signals. It has great potential for application in long-distance oil pipeline and subsea pipeline inspection. However, the spatial distribution characteristics and propagation laws of magnetic signals are not yet clear, which makes the MTM passive detection. In this study, a three-dimensional mathematical model of the magnetic field distribution of the stress concentration zone outside the pipe was established based on the boundary conditions. For the two cases in which the stress concentration zone was located at the top and bottom of the inner wall of the pipe, the model was solved by finite element analysis. The variation law of the magnetic signal outside the pipe was analyzed, and experiments were designed to verify the model. The results show that the shape of the magnetic memory signal remained unchanged after passing through the pipe wall. As the magnetic permeability of the pipe medium is much larger than that of air, the magnetic memory signal is significantly attenuated after penetrating the pipe wall. As the detection height increases, the magnetic induction outside the tube decays exponentially. The results also prove that the magnetic tomography method can detect the stress concentration zone at any position of the pipeline, and the detection accuracy is higher when it is located at the top of the pipeline.

Metal Surface Defect Detection Method Based on TE01 Mode Microwave.

With the aim of addressing the difficulty of detecting metal surface cracks and corrosion defects in complex environments, we propose a detection method for metal surface cracks and corrosion defects based on TE01-mode microwave. The microwave detection equations of cracks and corrosion defects were established by the Maxwell equations when the TE01 mode was excited by microwaves, and the relationship model between the defect size and the microwave characteristic quantity was established. A finite integral simulation model was established to analyze the influence of defects on the microwave electric field, magnetic field, and tube wall current in the rectangular waveguide, as well as the return loss at the defect; an experimental platform for the detection of metal surface cracks and corrosion defects was built. The absolute value of the return loss of the microwave reflected wave increased, and with the increase of the defect width, the microwave detection frequency at the defect decreased. The TE01-mode microwave has good detection ability for metal surface cracks and corrosion defects and can effectively detect cracks with a width of 0.3 mm.

A Multi-Wall Sn/SnO2 @Carbon Hollow Nanofiber Anode Material for High-Rate and Long-Life Lithium-Ion Batteries.

Multi-wall Sn/SnO2 @carbon hollow nanofibers evolved from SnO2 nanofibers are designed and programable synthesized by electrospinning, polypyrrole coating, and annealing reduction. The synthesized hollow nanofibers have a special wire-in-double-wall-tube structure with larger specific surface area and abundant inner spaces, which can provide effective contacting area of electrolyte with electrode materials and more active sites for redox reaction. It shows excellent cycling stability by virtue of effectively alleviating pulverization of tin-based electrode materials caused by volume expansion. Even after 2000 cycles, the wire-in-double-wall-tube Sn/SnO2 @carbon nanofibers exhibit a high specific capacity of 986.3 mAh g-1 (1 A g-1 ) and still maintains 508.2 mAh g-1 at high current density of 5 A g-1 . This outstanding electrochemical performance suggests the multi-wall Sn/SnO2 @ carbon hollow nanofibers are great promising for high performance energy storage systems.