Ecosystem service benefits and costs of deep-sea ecosystem restoration.

Deep-sea ecosystems are facing degradation which could have severe consequences for biodiversity and the livelihoods of coastal populations. Ecosystem restoration as a natural based solution has been regarded as a useful means to recover ecosystems. The study provides a social cost-benefit analysis for a proposed project to restore the Dohrn Canyon cold water corals and the deep-sea ecosystem in the Bay of Naples, Italy. By incorporating ecosystem service benefits and uncertainties related to a complex natural-technological-social system surrounding restoration activities, the study demonstrated how to evaluate large-scale ecosystem restoration activities. The results indicate that an ecosystem restoration project can be economic (in terms of welfare improvement) even if the restoration costs are high. Our study shows the uncertainty associated with restoration success rate significantly affects the probability distribution of the expected net present values. Identifying and controlling the underlying factors to improve the restoration successful rate is thus crucial.

Valuing high-seas ecosystem conservation.

The high seas provide a variety of ecosystem services that benefit society. There have, however, been few attempts to quantify the human welfare impacts of changes to the delivery of these benefits. We assessed the values of several key ecosystem service benefits derived from protecting ecosystems in the high seas of the Flemish Cap through choice experiments conducted in Canada, Norway, and Scotland. Rather than solely eliciting public willingness to pay, we also explored the determinants of variance in the estimates of willingness to pay. We aimed to determine how much respondents were willing to pay for high-seas ecosystems conservation, which factors influence individuals' willingness to pay, and whether individuals in Canada had a higher willingness to pay relative to those living in Norway and Scotland. This latter point captures distance-decay effects. On average, the public placed positive value on conserving high-seas ecosystems and on developing economic activities related to the exploitation and exploration of marine resources, despite a lack of awareness and familiarity with these environments. Distance-decay effects on willingness to pay were not clear. Scots had the highest willingness to pay and the Norwegians the lowest willingness to pay for all attributes, with the only exception being willingness to pay for a large increase in new jobs, in which case Canadians' willingness to pay was higher than Scots'. The public's willingness to pay was influenced by sociodemographic characteristics and their perceptions of high-seas ecosystems. Our results provide evidence of the impacts of high-seas governance on human welfare and that improved governance could increase the value people place on high-seas ecosystems and the services they produce.

La alta mar proporciona una variedad de servicios ambientales que benefician a la sociedad. Sin embargo, ha habido pocos intentos por cuantificar los impactos al bienestar humano ocasionados por los cambios en la entrega de estos beneficios. Analizamos los valores de varios beneficios importantes de los servicios ambientales derivados de la protección al ecosistema en la alta mar del Cabo Flamenco por medio de experimentos de elección realizados en Canadá, Noruega y Escocia. En lugar de sólo suscitar la voluntad pública para pagar, también exploramos las determinantes de la varianza en las estimaciones de la voluntad para pagar. Nuestro objetivo fue determinar cuánto están dispuestos a pagar los respondientes por la conservación de los ecosistemas de alta mar, cuáles factores influyen sobre la voluntad para pagar de cada individuo y si los individuos en Canadá tenían una mayor voluntad para pagar que aquellos individuos que viven en Noruega y en Escocia. Este último punto captura los efectos de la descomposición por distancia. En promedio, el público le colocó un valor positivo a la conservación de los ecosistemas de alta mar y al desarrollo de actividades económicas relacionadas con la explotación y la exploración de los recursos marinos, a pesar de la falta de conocimiento y familiaridad con estos ambientes. Los efectos de la descomposición por distancia sobre la voluntad para pagar no estuvieron claros. Los escoceses tuvieron la mayor voluntad para pagar y los noruegos la menor voluntad para pagar por todos los atributos, siendo la única excepción la voluntad para pagar por un incremento de trabajos nuevos, en cuyo caso, la voluntad de los canadienses fue más alta que la de los escoceses. La voluntad del público para pagar estuvo influenciada por las características sociodemográficas y su percepción de los ecosistemas de alta mar. Nuestros resultados proporcionan una evidencia de los impactos que tiene la gestión de alta mar sobre el bienestar humano y que la gestión mejorada podría incrementar el valor que las personas le ponen a los ecosistemas de alta mar y a los servicios que producen.

Have environmental preferences and willingness to pay remained stable before and during the global Covid-19 shock?

This study tests the stability of environmental preferences and willingness to pay (WTP) values using a discrete choice experiment (DCE) across three countries pre and post the peak of the first wave of the Covid-19 pandemic. A DCE examining the public's preferences for alternative environmental management plans on the high seas, in the area of the Flemish Cap, was carried out in Canada, Scotland and Norway in late 2019 and was rerun in early May 2020 shortly after the Covid-19 pandemic had officially peaked in the three countries. The same choice set sequence is tested across the two periods, using different but nationally representative samples in each case. Entropy balancing, a multivariate reweighting method, is used to achieve covariate balance between the pre and post Covid samples in the analysis. The results suggest that both preferences and WTP remain relatively stable in the face of a major public health crisis and economic upheaval.

More than two decades of Agri-Environment schemes: Has the profile of participating farms changed?

The agri-food sector is under increased pressure from consumers to improve on the sustainability of production processes. Policies that incentivise farmers to improve environmental performance, such as agri-environment schemes (AES), are increasingly important. Understanding the choice to participate in these programmes aids policymakers in designing schemes that meet participation and environmental goals. While a number of studies have investigated the decision using cross-sectional data on one or multiple locations, very few have used longitudinal data to investigate the impact of institutional changes over time. Using Ireland as a case study, this paper uses a nationally representative panel of data spanning 23 years to model the impact of scheme and policy changes on the type of farms participating in AES. This paper argues that environmental issues surrounding intensive farms (such as the loss of nutrients and sediment to water and greenhouse gas emissions) are not being optimally addressed in scheme design and further development of such programmes is needed to reduce negative environmental impacts.

Participation in agri-environmental schemes: A contingent valuation study of farmers in Ireland.

Agri-environment schemes (AES) are an important part of agricultural policy within Europe. They seek to achieve important goals with regards to biodiversity and the protection of natural resources while also helping to maintain culturally important landscapes and agricultural practices. Participation rates have been an important area of research into assessing the success of AES. Within Ireland and more broadly across Europe, systematic non-participation in AES has been observed. Certain farm and farmer types have been found more likely to participate. In this paper a contingent valuation exercise is conducted that assesses how AES payment levels impact on the participation decision of farmers. A bivariate probit with sample selection is utilised to account for farmers who are unwilling to participate regardless of payment levels. This allows for a more accurate estimation of farmer willingness-to-accept to participate in the hypothetical AES presented. It also offers insight into the characteristics of farmers who are unlikely to ever participate in these schemes. From the results it appears a significant proportion (30%) of farmers are unlikely to ever participate in AES, with the remaining open to participation depending on the compensation offered. It is argued that increased compensation levels may increase participation rates among some farmers who to date have been unlikely to participate.

Estimating the non-market benefit value of deep-sea ecosystem restoration: Evidence from a contingent valuation study of the Dohrn Canyon in the Bay of Naples.

It is increasingly recognized that restoration actions in marine environments are required in order to deal with continued habitat degradation and to support conservation strategies. Restoration success is judged on the ecological outcomes but with limited resources the magnitude of the societal benefits achieved is an important consideration for policy makers. This study demonstrates how the potential non-market benefit value of a deep-sea restoration project might be assessed. The contingent valuation method is employed to elicit the Italian population's willingness to pay for the restoration of the Dohrn deep-sea canyon in the Bay of Naples. Sample selection models that control for the impact of protest zero bidders on benefit value estimation are compared to more traditional modelling approaches. The results indicate a positive willingness to pay for the restoration of the canyon ecosystem and the importance of accounting for protest zero bidders in contingent valuation studies, especially when the environmental good is unfamiliar to respondents. The paper argues that the inclusion of non-market benefit values is particularly important in assessing the potential for marine ecosystem restoration if a true reflection of the value to society of restoring such habitats are to be correctly captured.

Defining and quantifying China's ocean economy.

In recent years, the Chinese government has been increasingly supportive of the development of the ocean economy, implementing several national ocean-related strategies. For the first time, China's 12th five-year Plan for National and Social Development (2011-2015) includes "developing the ocean economy" as a key national development strategy for the country. Because of this, the demand for ocean economic statistics and indicators is growing rapidly. The aim of this paper is to define and quantify the value of the major ocean industries in China and to examine the growth in the major Chinese ocean industries in the period 2001 to 2010. The paper also outlines a methodology that provides a robust quantification of the marine sector over time. It finds that in 2010 the major ocean industries in China contributed $239.09 billion to the national economy and employed over 9 million individuals.

Examining labelling effects within discrete choice experiments: an application to recreational site choice.

Data from a discrete choice experiment aimed at eliciting the demand for recreational walking trails on farmland in Ireland is used to explore whether some respondents reach their choices solely on the basis of the alternative's label. To investigate this, this paper exploits a discrete mixtures approach that also encompasses continuous distributions to reflect the heterogeneity in preferences for the attributes and alternatives. We find evidence that a proportion of respondents choose on the basis of the label only and that differences emerge between rural and urban respondents. We provide a number of alternative explanations for why this may occur. Results highlight a large impact on welfare measures when we accommodate the fact that a proportion of respondents choose on the basis of the label only.

The value of blue-space recreation and perceived water quality across Europe: A contingent behaviour study.

This study estimates the value of recreational visits to blue-space sites across 14 EU Member States, representing 78% of the Union's population. Across all countries surveyed, respondents made an average of 47 blue-space visits per person per year. Employing travel cost and contingent behaviour methods, the value of a visit is estimated at €41.32 which adds up to a recreational value of €631bn per year for the total adult population surveyed. Using the Bathing Water Directive's water quality designation, the analysis shows that a one-level improvement in water quality leads to 3.13 more visits (+6.67%), whereas a one-level deterioration leads to 9.77 fewer annual visits (-20.83%). This study provides valuations of benefits of recreation and changes of recreational values due to changes in surface water quality, which can be compared to the implementation and monitoring costs of efforts under the EU's Bathing Water, Water Framework and Marine Strategy Framework Directives.

Recreational boating site choice and the impact of water quality.

This paper examines whether water quality has an effect on recreational boating activity. The analysis is based on survey data collected by face-to-face interviews with recreational visitors to 10 waterway sites across Ireland. We model the respondent's choice decision to travel to a specific site for the purposes of beginning their recreational boating activity. Water quality data is from European Union Water Framework Directive monitoring stations. Across recreational sites, which have generally high water quality levels within our sample, we find that boaters favour sites with better water quality; as indicated by biological oxygen demand and phosphates metrics. We also find that for each additional 10 km distance from respondents' homes the probability that a site is visited declines by up to 10%. Preferences for other site attributes, such as boat slipways, parking and toilet facilities, were counter to expectation but reflects the fact that all boat users do not necessarily access or need all facilities provided.

Alternative treatments of the cost of time in recreational demand models: an application to whitewater kayaking in Ireland.

The measurement of travel costs in recreational demand modeling has been a contentious issue for many decades. This article explores the use of a number of alternative methods of incorporating time costs in the travel cost modeling process. Travel cost values where the opportunity cost of time is excluded, where it is included as a percentage of the individual's reported wage rate and where it based on an estimated wage from a secondary data source (the European Community Household Panel) are compared and then used in a conditional logit model to estimate the demand for whitewater kayaking in Ireland. We then evaluate the effect of different treatments of the cost of travel time on the welfare impacts of a number of different management scenarios for kayaking rivers in Ireland, and find that statistically significant differences emerge.

Asymmetric acyl-transfer promoted by readily assembled chiral 4-N,N-dialkylaminopyridine derivatives.

The development of a new class of chiral 4-N,N-dialkylaminopyridine acyl-transfer catalysts capable of exploiting both van der Waals (pi) and H-bonding interactions to allow remote chiral information to stereochemically control the kinetic resolution of sec-alcohols with moderate to excellent selectivity (s = 6-30). Catalysts derived from (S)-alpha,alpha-diarylprolinol are considerably superior to analogues devoid of a tertiary hydroxyl moiety and possess high activity and selectivity across a broad range of substrates.

Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues.

We report the development of a new class of readily prepared chiral 4-(pyrrolidino)-pyridine catalysts capable of exploiting both van der Waals (pi) and H-bonding interactions, thus allowing remote chiral information to stereochemically control the kinetic resolution of sec-alcohols.

On the regiochemistry of nucleophilic attack on 2-halo pi-allyl complexes. 4. The effect of silver acetate and nucleophile concentrations in competitive nucleophilic attack with malonate and phenoxide nucleophiles.

2,3-Dibromo-1-propene or its allyl carbonate analogue are ionized under Pd catalysis to generate the 2-bromo Pd-pi-allyl complex (triphenylphosphine ligand), which alkylates with malonate nucleophile at the terminal position. The presence of acetate ion in the reaction mixture results in some malonate attack being redirected to the central carbon. The acetate ion can come from the ionization of 1-acetoxy-2-bromo-2-propene or by the addition of silver acetate to the reaction mixture. The addition of phenoxide ion to the reaction also causes the same regiochemical phenomena, although harder anions such as methoxide exert no such effect.

Allylic ionization versus oxidative addition into vinyl C-X bonds by Pd with polyfunctional olefin templates.

The chemoselectivity of activation by a (PPh3)4Pd catalyst on a series of small, olefin-based compounds that were substituted with a variety of allylic and vinylic functional groups was studied. Of particular note, the allylic acetate of 1-acetoxy-2-bromo-2-propene (7) was selectively ionized by Pd in the presence of a malonate nucleophile, while oxidative addition of the C-Br bond to Pd occurred exclusively in the presence of a boronic acid nucleophile. When the acetate nucleophile was used, no ionization of the acetate leaving group occurred at all, which was proven by the use of deuterium-labeled substrates (e.g., 11). This report demonstrates that the nucleophile interacts in some way with Pd prior to catalyst activation of the substrate. Certainly in the case of the malonate nucleophile, this is without precedent and contradicts the central dogma of how these proposed catalytic cycles operate.

A novel general route for the preparation of enantiopure imidazolines.

A novel procedure for the preparation of enantiopure 1,4-disubstituted 2-imidazolines is reported. Enantiopure beta-amino alcohols are converted into N-hydroxyethylamides, which are reacted with excess thionyl chloride, or with thionyl chloride followed by phosphorus pentachloride to yield N-chloroethylimidoyl chlorides. These intermediates are treated with amines and anilines to produce N-chloroethylamidines, which are converted into imidazolines upon workup with aqueous hydroxide. The method is simple and efficient and has been used to prepare a wide variety of enantiopure imidazolines, in a modular fashion, from readily available amino alcohols.

Preparation of enantiopure biimidazoline ligands and their use in asymmetric catalysis.

A convenient new method for the preparation of 2,2'-biimidazolines is reported. Amino alcohols were reacted with dimethyl oxalate, and the product hydroxy amides converted into chloroamides by reaction with thionyl chloride. Treatment with PCl5, followed by diamines (ethanediamine, propane-1,3-diamine, 2,2-dimethylpropane-1,3-diamine) furnished a series of enantiopure tricyclic biimidazolines. Complexes of two of the ligands with PdCl2 were prepared and their X-ray crystal structures were determined. The biimidazolines were tested as ligands for asymmetric Pd-catalysed allylations. Moderate enantioselectivity (up to 80% ee) was found for the reaction of dimethyl malonate with diphenylallyl acetate, with the 5,7,5 fused tricyclic systems outperforming the 5,6,5 analogues. The corresponding reaction of pentenyl acetate gave lower enantioselectivity (44-57% ee), and proved very sensitive to the donor strength of the ligands, the stronger donors giving lower yields. The results provide a further demonstration of the value of the 'tunability' of imidazoline ligands.