Multicriteria Decision-Making Technique for Choosing the Optimal Ammonia Energy Share in an Ammonia-Biodiesel-Fueled Reactivity-Controlled Compression Ignition Engine.

Low-temperature combustion paired with the use of carbon-free ammonia and carbon-neutral biofuels is a novel approach for improving performance, reducing greenhouse gases, and reducing regulated emissions. Reactivity-controlled compression ignition (RCCI), a low-temperature combustion technology, dramatically reduces NOx and smoke emissions compared to traditional engines. Ammonia can be projected as a good transit fuel in the journey toward achieving net zero emissions and cleaner energy. This study examines the impact of ammonia energy premixing fraction (AEPF) (20, 30, 40, and 50%) as a low-reactive fuel (LRF) and algal biodiesel as a high-reactive fuel on the performance and emission characteristics of a single-cylinder, water-cooled 3.5 kW CI engine at a constant speed of 1500 rpm under various loading conditions. The research results indicate that the 40% ammonia share RCCI mode exhibited a reduction in carbon dioxide (CO2) by 14.16%, nitrogen oxide (NOx) by 22.6%, and smoke by 42.1%, with an 11.5% improvement in thermal efficiency compared to the neat biodiesel-fueled conventional engine. Furthermore, the analytical hierarchy process (AHP) will be used in conjunction with the technique for order of preference by similarity to ideal solution (TOPSIS) of multiple criteria decision-making techniques to determine the optimal energy share in the RCCI combustion with the goal of achieving superior thermal efficiency and lower emissions. According to the AHP-TOPSIS study findings, AEPF40 is the best choice for all engine loads.

Experimental Studies to Reduce Usage of Fossil Fuels and Improve Green Fuels by Adopting Hydrogen-Ammonia-Biodiesel as Trinary Fuel for RCCI Engine.

This study investigates the feasibility of hydrogen addition to achieve lower emissions and higher thermal efficiency in an ammonia-biodiesel-fueled reactivity-controlled compression ignition (RCCI) engine. A single-cylinder light-duty water-cooled compression ignition (CI) engine was adapted to run in RCCI combustion with port-injected ammonia and hydrogen as low reactive fuel (LRF) and direct-injected algal biodiesel as high reactive fuel (HRF). In our earlier study, the ammonia substitution ratio (ASR) was optimized as 40%. To optimize fuel and engine settings, hydrogen is added in quantities ranging from 5 to 20% by energy share. The combustion, performance, and emission characteristics were investigated for the trinary fuel operation. The result shows that the 20% hydrogen premixing with 40% ammonia-biodiesel RCCI operation increased the peak cylinder pressure (CP), peak heat release rate (HRR), and cumulative heat release rate (CHRR) by 15.12, 25.15, and 26.68%, respectively. Ignition delay (ID) and combustion duration (CD) were decreased by 15.53 and 11.24%, respectively. The combustion phasing angle was advanced by 4 °CA. The brake thermal efficiency (BTE) was improved by 15.49%, and brake specific energy consumption (BSEC) was reduced by 21.92%. While the nitrogen oxide (NOx) level was significantly increased by about 31.82%, the hydrocarbon (HC), carbon monoxide (CO), smoke, and exhaust gas temperature (EGT) were reduced by 24.53, 28.16, 25.82, and 17.47% as compared to the optimized ASR40% combustion.

Compatibility Effects of Waste Cooking Oil Biodiesel Blend on Fuel System Elastomers in Compression Ignition Engines.

Alternative energy sources, such as biodiesel, play a vital role in environmental protection. Waste cooking oil (WCO) biodiesel has promising applications in compression ignition engines. A major problem regarding biodiesel implementation is the deterioration and materials incompatibility of existing fuel system components with biodiesel. Variations in the composition of fuel prompted by the inclusion of biodiesel cause a variety of issues in diesel engine fuel systems where the elastomer is generally utilized as the fuel hose material and sealings. In this experimental work, the effects of the diesel and WCO biodiesel blends (B8, B16, B24, and B100) on Buna-N, ethylene propylene rubber (EPR), and polystyrene (PS) were examined by the immersion test, which was conducted for 160 h at various immersion temperatures of 30, 60, and 80 °C, respectively. The study also showed that the use of elastomer materials like Buna-N, EPR, and PS in diesel engines fueled up to 20% WCO biodiesel blends is advantageous; the overall compatibility improves by 100% compared to that obtained using neat diesel. The outcome revealed remarkable behavior changes, including a minor increase in volume and a slight loss in tensile strength and hardness compared to that observed using neat diesel fuel. The expansion of rubber materials increases over 60 °C, although the rate of this process decreases above 80 °C. It has been found that the expansion of rubber materials is unaffected by the acid concentration of the WCO biodiesel blends but significantly affected by the moisture content.

Experimental Investigation on the PCCI Engine Fueled by Algal Biodiesel Blend with CuO Nanocatalyst Additive and Optimization of Fuel Combination for Improved Performance and Reduced Emissions at Various Load Conditions by RSM Technique.

Fossil fuel depletion and environmental pollution are paramount problems the world faces. Despite several measures, the transportation industry is still battling to manage these issues. A combined approach of fuel modification for low-temperature combustion with combustion enhancers could offer a breakthrough. Due to their properties and chemical structure, biodiesels have piqued the interest of scientists. Studies have asserted that microalgal biodiesel might be a viable alternative. Premixed charge compression ignition (PCCI) is an easily adoptable promising low-temperature combustion strategy in compression ignition engines. The objective of this study is to identify the optimal blend and catalyst measure for improved performance and reduced emissions. Microalgae biodiesel at various proportions (B10, B20, B30, and B40) was amalgamated with CuO nanocatalyst and tested to arrive at the right concoction of biodiesel with nanoparticles in a 5.2 kW CI engine for different load conditions. The PCCI function warrants that about 20% of the fuel supplied is vaporized for premixing. Finally, the interplay factors of the independent variables of the PCCI engine were then explored by response surface methodology (RSM) to determine the optimal level of desired dependent and independent variables. The RSM experiment findings suggest that the best biodiesel and nanoparticle concoctions at 20%, 40%, 60%, and 80% loads were B20CuO76, B20Cu60, B18CuO61, and B18CuO65, respectively. These findings were experimentally validated.

Investigation on Ammonia-Biodiesel Fueled RCCI Combustion Engine Using a Split Injection Strategy.

Advanced combustion concepts in compression ignition are emerging as one of the most promising solutions to reduce nitrogen oxides (NOx) and particle emissions without sacrificing fuel efficiency. Among many advanced combustion concepts, reactive controlled compression ignition (RCCI) can achieve a wider working range. In this study, to implement RCCI operation, ammonia gas is introduced through the manifold as a low-reactive fuel, and biodiesel is injected directly as a high-reactivity fuel with a 40:60 energy ratio. The effect of biodiesel split ratio in a split injection strategy (pre- and main injections) is examined under varied load conditions, and the results are compared with ammonia/biodiesel single injection. Results indicate that the use of the 45% biodiesel split ratio at full load boosts the peak in-cylinder pressure and heat release rate and shifts the peak occurrence toward the top dead center (TDC). An increase in brake thermal efficiency (BTE) to 36.22% and reduced brake specific energy consumption (BSEC) to 8.75 MJ/kWh are 12.33% higher and 19.31% lower than ammonia/biodiesel single injection. Emissions of HC, CO, and smoke opacity were reduced to 50 ppm, 0.098% vol, and 15.6%, which are 34.21, 39.13, and 33.89% lower, while the emission of NOx was increased to 615 ppm, which is 36.06% higher than the single-injection ammonia/biodiesel RCCI combustion.

Investigation into the Ideal Concoction for Performance and Emissions Enhancement of Jatropha Biodiesel-Diesel with CuO Nanoparticles Using Response Surface Methodology.

The present work covers the preparation of biodiesel from jatropha oil through the transesterification process followed by its characterization, and furthermore, performance and emission analyses were done in terms of blending biodiesel with fossil diesel and CuO nanoparticles. Jatropha biodiesel blends (B10, B20, and B30) were chosen for this preliminary investigation based on the observation that B20 outperformed other blends. Next stage B20 with copper oxide (CuO) nanoparticle concentrations of 25, 50, 75, and 50 ppm are used to examine the performance and emission characteristics of a constant speed single cylinder, 4-stroke, 3.5 kW compression ignition (CI) engine. Finally, The response surface methodology (RSM) was utilized to determine the optimal nanoparticle concentration for B20. The results revealed that the blend of B20 with 80 ppm nanoparticles had the highest desirability (0.9732), and the developed RSM model was able to predict engine responses with a mean absolute percentage error (MAPE) of 3.113%. A confirmation test with an error in prediction of less than 5% verified the model's adequacy. When comparing optimized B20CuO80 to diesel, brake specific energy consumption (BSEC) increased by 8.49% and brake thermal efficiency (BTE) was lowered by 3.34%. Hydrocarbon (HC), carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxide (NOx), and smoke emissions were reduced by 3.66% and 2.88%, 4.78%, 22.9%, and 20.54%, respectively, at 80% load. As a result, the B20 blend with nanoparticle concentrations of 80 ppm may be used in current diesel engines without engine modification.

Experimental Investigation for Determining an Ideal Algal Biodiesel-Diesel Blend to Improve the Performance and Mitigate Emissions Using a Response Surface Methodology.

The ongoing depletion of the world's fossil fuel sources and environmental damage has compelled the quest for alternative energy. Excellent characteristics of biodiesel include its renewable nature, safety, absence of sulfur, environmental advantages, and biodegradability, which can eradicate the above problems. In this study, algal oil was characterized to obtain the fatty acid profile, and the free fatty acid value of algal oil suggested a two-step process of esterification and transesterification for efficient biodiesel production. The performance and emission results of biodiesel and its blends (B10, B20, and B30) were investigated in a constant speed, single-cylinder, 4-stroke, 3.5 kW compression ignition engine at different loads for arriving at an appropriate fuel blend ratio. The response surface methodology technique is used to predict the ideal composition of microalgae-diesel using the experimental data with due weightage for the optimization criterion. The predicted blend ratio of B25 was tested on the engine and authenticated. The findings recorded an improvement in brake thermal efficiency to 31.42% and reduction in brake specific energy consumption to 9.82 MJ/kW h, unburned hydrocarbon to 85 ppm, carbon monoxide to 0.164% v/v, carbon dioxide to 4.115% v/v, nitrogen oxides to 691 ppm, and smoke opacity to 16.93%.