Current insights into environmental acetochlor toxicity and remediation strategies.

Acetochlor is a selective pre-emergent herbicide that is widely used to control annual grass and broadleaf weeds. However, due to its stable chemical structure, only a small portion of acetochlor exerts herbicidal activity in agricultural applications, while most of the excess remains on the surfaces of plants or enters ecosystems, such as soil and water bodies, causing harm to the environment and human health. In recent years, researchers have become increasingly focused on the repair of acetochlor residues. Compared with traditional physical and chemical remediation methods, microorganisms are the most effective way to remediate chemical pesticide pollution, such as acetochlor, because of their rich species, wide distribution, and diverse metabolic pathways. To date, researchers have isolated and identified many high-efficiency acetochlor-degrading strains, such as Pseudomonas oleovorans, Klebsiella variicola, Bacillus subtilus, Rhodococcus, and Methylobacillus, among others. The microbial degradation pathways of acetochlor include dechlorination, hydroxylation, N-dealkylation, C-dealkylation, and dehydrogenation. In addition, the microbial enzymes, including hydrolase (ChlH), debutoxylase (Dbo), and monooxygenase (MeaXY), responsible for acetochlor biodegradation are also being investigated. In this paper, we review the migration law of acetochlor in the environment, its toxicity to nontarget organisms, and the main metabolic methods. Moreover, we summarize the latest progress in the research on the microbial catabolism of acetochlor, including the efficient degradation of microbial resources, biodegradation metabolic pathways, and key enzymes for acetochlor degradation. At the end of the article, we highlight the existing problems in the current research on acetochlor biodegradation, provide new ideas for the remediation of acetochlor pollution in the environment, and propose future research directions.

Three-dimensional force-tactile sensors based on embedded fiber Bragg gratings in anisotropic materials.

Three-dimensional force-tactile sensors have attracted much attention for their great potential in the applications of human-computer interaction and bionic intelligent robotics. Herein, a flexible haptic sensor based on dual fiber Bragg gratings (FBGs) embedded in a bionic anisotropic material is proposed for the detection of 3D forces. To achieve the discrimination of normal and tangential force angles and magnitudes, FBGs were orthogonally embedded in a flexible silicone cylinder for force determination. Fe3O4 nanoparticles were used as a modifying agent to induce anisotropic elasticity of the silicone structure to improve the angle detection resolution. The results show that the flexible tactile sensor can detect the angle and magnitude of the 3D force.

The bound state in the continuum in flexible terahertz metasurfaces enabled sensitive biosensing.

The combination of a flexible device and novel electromagnetic resonances offers new dimensions to manipulate electromagnetic waves and promises new device functionalities. In this study, we experimentally demonstrate a flexible metasurface that can support the bound state in the continuum (BIC) in the terahertz regime. The metasurface consists of toroidal dipole resonant units on top of the flexible polyimide substrate, which can support a terahertz Friedrich-Wintgen BIC resonance, and the resonance characteristics can be tuned by changing the parameters of the coupling unit among two resonant modes. The BIC resonances under different bending conditions are analyzed and compared, showing decent mechanical robustness. The sensing application is demonstrated by combining Fetal Bovine Serum with the flexible BIC metasurface. The measured minimum detectable concentration is 0.007 mg mL-1. Benefiting from the mechanical flexibility and BIC resonance characteristics, our approach can effectively manipulate terahertz waves and have potential applications in the realization of multifunctional and flexible photonic devices.

Compact Harmonic Vernier Sensor Based on an In-Fiber FPI with Three Reflector System for Simultaneous Gas Pressure and Temperature Measurement.

In this work, we proposed a sensitivity-enhanced temperature sensor, a compact harmonic Vernier sensor based on an in-fiber Fabry-Perot Interferometer (FPI), with three reflective interfaces for the measurement of gas temperature and pressure. FPI consists of air and silica cavities formulated by single-mode optical fiber (SMF) and several short hollow core fiber segments. One of the cavity lengths is deliberately made larger to excite several harmonics of the Vernier effect that have different sensitivity magnifications to the gas pressure and temperature. The spectral curve could be demodulated using a digital bandpass filter to extract the interference spectrum according to the spatial frequencies of resonance cavities. The findings indicate that the material and structural properties of the resonance cavities have an impact on the respective temperature sensitivity and pressure sensitivity. The measured pressure sensitivity and temperature sensitivity of the proposed sensor are 114 nm/MPa and 176 pm/°C, respectively. Therefore, the proposed sensor combines ease of fabrication and high sensitivity, making it great potential for practical sensing measurements.

Learned iterative shrinkage and thresholding algorithm for terahertz sparse deconvolution.

Terahertz sparse deconvolution based on an iterative shrinkage and thresholding algorithm (ISTA) has been used to characterize multilayered structures with resolution equivalent to or finer than the sampling period of the measurement. However, this method was only studied on thin samples to separate the overlapped echos that can't be distinguished by other deconvolution algorithms. Besides, ISTA heavily depends on the convolution matrix consisting of delayed incident pulse, which is difficult to precisely extricate from the reference signal, and thereby fluctuations caused by noise are occasionally treated as echos. In this work, a terahertz sparse deconvolution based on a learned iterative shrinkage and thresholding algorithm (LISTA) is proposed. The method enclosed the matrix multiplication and soft thresholding in a block and cascaded multiple blocks together to form a deep network. The convolution matrices of the network were updated by stochastic gradient descent to minimize the distance between the output sparse vector and the optimal sparse representation of the signal, and subsequently the trained network made more precise estimation of the echos than ISTA. Additionally, LISTA is notably faster than ISTA, which is important for real-time tomographic-image processing. The algorithm was evaluated on terahertz tomographic imaging of a high-density poly ethylene (HDPE) sample, revealing obvious improvements in detecting defects of different sizes and depths. This technique has potential usage in nondestructive testings of thick samples, where echos reflected by minor defects are not discernible by existed deconvolution algorithms.

Active control of terahertz waves based on p-Si hybrid PIT metasurface device under avalanche breakdown.

Active control of terahertz waves is a critical application for terahertz devices. Silicon is widely used in large-scale integrated circuit and optoelectronic devices, and also shows great potential in the terahertz field. In this paper, a p-Si hybrid metasurface device is proposed and its terahertz characteristics under avalanche breakdown effect is investigated. In the study, a plasmon-induced transparency (PIT) effect caused by the near-field coupling of the bright mode and the dark mode is observed in the transmission spectrum. Due to avalanche breakdown effect, the resonance of the PIT metamaterial disappears as the current increased. Carriers existed in the interface between the metasurface and substrate result to a dipole resonance suppression. When the current continues increasing, the maximal modulation depth can reach up to 99.9%, caused by the avalanche effect of p-Si. Experimental results demonstrate that the avalanche breakdown p-Si can achieve a performance modulation depth, bringing much more possibilities for terahertz devices.

Improved TDM scheme and data extracting algorithm for polymerization evaluation.

To quickly evaluate holographic photopolymers with different formulations, the most effective method is to record a volume holographic grating in the samples and detect the grating's diffraction in real time. Since the volume grating is highly sensitive to incident angle, existing schemes need to precisely control many space-related parameters. This study proposes an improved scheme, in which two different sized spots are used to reduce the requirements for the overlap of the two spots and the installation precision of the samples. Transmittances, diffractive efficiencies and diffractive asymmetries are obtained at a high sampling rate, through a specifically designed algorithm with the data from uncalibrated high-speed photodiodes. The experimental results show that the proposed scheme performance well in evaluating holographic photopolymer.

Ultrafast volume holographic recording with exposure reciprocity matching for TI/PMMAs application.

The range of exposure for which the holographic reciprocity law holds in photopolymers, is mainly dependent on the light exposure intensity and polymerization rate between photo-initiator and monomers. Matching this is the key to improving performance. Characterization of the dependence on diffraction efficiency of the volume transmission gratings on holographic reciprocity matching of TI/PMMAs under different milliseconds with different thickness (1-3mm) has been carried out for the novel high-sensitive TI/PMMA polymers. Diffraction gratings can be recorded in TI/PMMAs under 20ms with the exposure intensity of 115mW/cm2. The physical and chemical mechanism under and after single shot exposure is analyzed which can be divided into three parts, namely, photo-induced polymerization, dark diffusion of photosensitive molecules, and counter-diffusion of photoproducts. Holographic properties of TI/PMMAs of different thickness (1-3mm) under different shingle-shot durations and repetition rates are investigated in detail as well. The diffraction efficiency reaches 67% with the response time of 15.69s. By this way, volume holographic gratings with no reciprocity failure can be recorded under multi-pulse exposure, with high grating strength and rapid sensitivity in TI/PMMAs, which indicates the volume holographic memories have the potential for recording and storing transient information in life and in the military.

Terahertz wave near-field compressive imaging with a spatial resolution of over λ/100.

We demonstrate terahertz (THz) wave near-field imaging with a spatial resolution of ∼4.5 µm using single-pixel compressive sensing enabled by femtosecond-laser (fs-laser) driven vanadium dioxide (VO2)-based spatial light modulator. By fs-laser patterning a 180 nm thick VO2 nanofilm with a digital micromirror device, we spatially encode the near-field THz evanescent waves. With single-pixel Hadamard detection of the evanescent waves, we reconstructed the THz wave near-field image of an object from a serial of encoded sequential measurements, yielding improved signal-to-noise ratio by one order of magnitude over a raster-scanning technique. Further, we demonstrate that the acquisition time was compressed by a factor of over four with 90% fidelity using a total variation minimization algorithm. The proposed THz wave near-field imaging technique inspires new and challenging applications such as cellular imaging.

Giant dual-mode graphene-based terahertz modulator enabled by Fabry-Perot assisted multiple reflection.

We report a high-performance terahertz (THz) modulator with dual operation mode. For the pulse operation mode, the proposed THz modulator has the advantage of high modulation depth (MD) and can operate in a broadband frequency range. We have experimentally achieved a MD larger than 90% for the fifth-order pulse THz echo at 0.8 THz, and the MD stays larger than 75% in a broadband frequency range larger than 1 THz, whereas, for the coherent operation mode, the Fabry-Perot (F-P) interference effect has been taken into consideration and a MD larger than 75% at 0.76 THz has also been realized.

Ultrafast volume holographic storage on PQ/PMMA photopolymers with nanosecond pulsed exposures.

Ultrafast holographic recording in bulk phenanthrenequinone dispersed poly (methyl methacrylate) photopolymers is experimentally examined under nanosecond pulsed exposure. A modified interference optical system is set to investigate the dark enhancement effect and real-time diffraction grating strength. Single transmission diffraction grating is recorded in a 6 nanosecond pulse exposure. Grating enhancement formation with different pulse quantity, repetition rate and spatial frequency are also measured. Diffraction efficiency is enhanced by increasing the pulse number as well as the single-pulse energy. The grating strength of 0.58 within 1.8 µs cumulative exposure time is obtained. Moreover, holographic reciprocity failure occurring in the ultrafast holographic storage is analyzed. This paper presents a practical support for PQ/PMMA photopolymers in applications of transient information holographic storage.

Improvement of ultrafast holographic performance in silver nanoprisms dispersed photopolymer.

This work demonstrates the grating formation of bulk nanoparticle polymer composites through an improved interference optical system under ultrafast nanoseconds exposure of a silver nanoprisms (NPs) dispersed photo-polymerizable mixture in the case of 532 nm wavelength. The polymerizable mixture is composed of phenathrenequinone (PQ) (photoinitiator) and methyl methacrylate (MMA) (monomer). The mechanism in this bulk nanoparticle polymer composite is analyzed by mixing nonlocal polymerization driven diffusion (NPDD) model and absorption modulation caused by the spatial concentration distribution difference of silver NPs. We find that the attenuation of diffraction efficiency under pulsed exposure is due to the reciprocity law failure. This work presents an analysis of the cause of reciprocity failure and improvement in holographic properties by doping silver NPs. The optimized photopolymer presents diffraction efficiencies as high as 51.4% with 1.8 µs cumulative pulsed exposure. Cumulative gratings strength is also enhanced by 70% while doping silver NPs under 1.5 µs cumulative pulsed exposure.

Giant impact of self-photothermal on light-induced ultrafast insulator-to-metal transition in VO2 nanofilms at terahertz frequency.

Ultrafast detection and switching of light are key processes in high-speed optoelectronic devices. However, the performances of VO2-based optoelectronics are strongly degraded by photothermal. The mechanism of the latter is still unclear. Here, by using femtosecond-laser (fs-laser) driven kinetic terahertz wave absorption, we quantitatively separate slow photothermal response and ultrafast photodoping response (e.g. light-induced insulator-to-metal transition) from second- to picosecond-timescales, and discover the competing interplay between them. With self-photothermal (mainly determined by fs-laser pulse repetition rate and pump fluence), the ultrafast transition time was degraded by 190% from 50 ps to 95 ps, the ultrafast transition threshold was decreased to 82% from 11mJ/cm2 to 9mJ/cm2, while the amplitudes of the two photoresponse are competing. Percolation theory, along with the macroscopic conductivity response, is used to explain the competing interplay. Our findings are relevant for designing and optimizing VO2-based ultrafast optoelectronic devices.

Ultrasensitive specific terahertz sensor based on tunable plasmon induced transparency of a graphene micro-ribbon array structure.

We proposed an ultrasensitive specific terahertz sensor consisting of two sets of graphene micro-ribbon with different widths. The interference between the plasmon resonances of the wide and narrow graphene micro-ribbons gives rise to the plasmon induced transparency (PIT) effect and enables ultrasensitive sensing in terahertz region. The performances of the PIT sensor have been analyzed in detail considering the thickness and refractive index sensing applications using full wave electromagnetic simulations. Taking advantage of the electrical tunability of graphene's Fermi level, we demonstrated the specific sensing of benzoic acid with detection limit smaller than 6.35 µg/cm2. The combination of specific identification and enhanced sensitivity of the PIT sensor opens exciting prospects for bio/chemical molecules sensing in the terahertz region.

Bi-fiber quasi-axis probe for photonic Doppler velocimetry for shock physics experiments.

Photonic Doppler velocimetry (PDV) has become a major domain velocity measurement technique for shock physics experiments. In this study, we propose and validate a bi-fiber quasi-axis probe for PDV that consists of a multimode source fiber and a single-mode detection fiber. This structure makes the received light by the probe totally reflected or scattered from the target, and, therefore, is free from the influence of unwanted return light. The light-receiving efficiency of the probe was calculated by the Monte Carlo method and was validated by static experiment. We validate that the feasibility of probe by dynamic experiments with measurement depth up to 6 cm. Above all, the bi-fiber quasi-axis probe is a promising supplementary probe for PDV for shock physics experiments.

Analysis of red blood cells' dynamic status in a simulated blood circulation system using an ultrahigh-speed simultaneous framing optical electronic camera.

Alterations in the morphologic and mechanical properties of red blood cells (RBCs) are considered direct indicators of blood quality. Current measures of characterizing these properties in vivo are limited by the complicated hemodynamic environment. To better evaluate the quality of fresh and stored blood, a new research platform was constructed to evaluate the hemodynamic characteristics of RBCs. The research platform consists mostly of a microfluidic chip, microscope, and ultrahigh-speed simultaneous framing optical electronic camera (USFOEC). The microfluidic chip was designed to simplify the complicated hemodynamic environment. The RBCs were diluted in erythrocyte preservative fluid and infused into the microfluidic channels. After approximately 600× magnification of using the microscope and camera, the RBCs' dynamic images were captured by the USFOEC. Eight sequential and blur-free images were simultaneously captured by the USFOEC system. Results showed that RBC deformation changed with flow velocity and stored RBCs were less sensitive to deformation (Kfresh < Kstored ). The frozen-stored RBCs were better able to sustain hydrodynamic stress (DI49day = 0.128 vs. DIfrozen = 0.118) than cold-stored RBCs but more sensitive to variations in flow speed (K49day = 1626.2 vs. Kfrozen = 1318.2). Results showed that the stored RBCs had worse deformability than fresh RBCs, but frozen-stored RBCs may incur less damage during storage than those stored at merely cold temperatures. This USFOEC imaging system can serve as a platform for direct observation of cell morphological and mechanical properties in a medium similar to a physiologic environment. © 2016 International Society for Advancement of Cytometry.

Dual-mode tunable terahertz generation in lithium niobate driven by spatially shaped femtosecond laser.

A new approach for dual-mode (namely broadband mode and narrowband mode) terahertz (THz) pulses generation in a single lithium niobate (LN) crystal excited by spatially shaped tilted-pulse-front femtosecond (fs) laser pulse was proposed and experimentally demonstrated. The two THz emission modes are generated simultaneously while spatially separated. Both central frequency and bandwidth of narrowband THz emission is controllable by in situ tuning the spatial modulation period and beam size of the fs-laser, and the broadband (0.1-1.5 THz) THz emission keeps almost unchanged while tuning the narrowband emission. Further optimization achieves the narrowband THz emission with energy spectral density up to 0.27 µJ/THz and with bandwidth narrowly down to 23 GHz. Such dual-mode THz source is useful for nonlinear THz optics, such as selected resonant THz excitation with broadband THz probe spectroscopy of crystalline matters.

Purified frequency modulation of a quantum cascade laser with an all-optical approach.

Purified frequency modulation (FM) is demonstrated in a standard middle-infrared quantum cascade laser by illuminating its front facet with two near-infrared (NIR) lasers. A 2 mW laser at 1550 nm is utilized to modulate the amplitude and frequency of a quantum cascade laser, and the associated amplitude modulation (AM) is suppressed by a 1.85 mW laser at 850 nm. Due to the hot carrier effect and the increment of electron temperature, the AM has been decreased. In addition, the free carrier concentration increases in the active region due to the two NIR illuminations, which enhance the FM. Purified FM is beneficial in improving the signal fidelity for free-space optical communication and high-speed FM spectroscopy.

Generation of 0.19-mJ THz pulses in LiNbO3 driven by 800-nm femtosecond laser.

A cylindrical lens telescope tilted-pulse-front pumping scheme was proposed for high energy terahertz (THz) pulse generation. This scheme allows higher pump energy to be used with lower saturation effects under high pump fluence, and higher THz generation efficiency was achieved within large range of pump energy. The optimum pump pulse duration and crystal cooling temperature for THz generation in LiNbO3 (LN) crystal were also researched systematically. Excited by 800-nm laser, up to 0.19 mJ THz pulse energy and 0.27% conversion efficiency was demonstrated under 800-nm 400-fs laser excitation with ~100-mJ pulse energy and 150-K LN cooling temperature.

Optimization of terahertz generation from LiNbO3 under intense laser excitation with the effect of three-photon absorption.

We proposed a three-dimensional model to simulate terahertz generation from LiNbO3 crystal under intense laser excition (up to ~50 mJ/cm2). The impact of three-photon absorption, which leads to free carrier generation and free carrier saturation (when pump fluence above ~10 mJ/cm2) on terahertz generation was investigated. And further with this model, we stated the optimized experimental conditions (incident postion, beam diameter, and pulse duration, etc) for maximum generation efficiency in commonly-used tilted-pulse-front scheme. Red shift of spectrum, spatial distribution "splitting" effects of emitted THz beam, and primilary experimental verification under intense laser excitation are given.