1.
Tetrahedron Lett
; 58(20): 1973-1975, 2017 05 17.
Artículo
en Inglés
| MEDLINE
| ID: mdl-28966404
RESUMEN
The interaction of various 1,2-dibromides with NEt3 under various conditions (THF and DMF, respectively) at different temperatures was investigated. Our results from these reactions show that substrate dependent dehydrobrominations compete with reductive debrominations. A comprehensive discussion of these competitive pathways is offered.
2.
Tetrahedron Lett
; 57(3): 285-287, 2016 Jan 20.
Artículo
en Inglés
| MEDLINE
| ID: mdl-26951759
RESUMEN
vic -Dibromides containing the α-bromocarbonyl or α-bromoaromatic moieties were reductively debrominated to furnish alkenes in high yield. o- and m-Anisidines but not p-anisidine were found to be effective debrominating agents. The reductive debrominations were found to be trans-stereospecific.