Efficient coupling between single mode fibers and glass chip waveguides via graded refractive index fiber tips.

Coupling characteristics between a single mode fiber (SMF) and a waveguide embedded in a glass chip via a graded index fiber (GIF) tip are investigated at a wavelength of 976 nm. The GIF tips comprise a coreless fiber section and a GIF section. A depressed cladding waveguide in a ZBLAN glass chip with a core diameter of 35 µm is coupled with GIF tips that have a range of coreless fiber and GIF lengths. An experimental coupling efficiency as high as 88% is obtained while a numerical simulation predicts 92.9% for the same GIF tip configuration. Since it is measured in the presence of Fresnel reflection, it can be further improved by anti-reflection coating. Additionally, it is demonstrated that a gap can be introduced between the chip waveguide and the GIF tip while maintaining the high coupling efficiency, thus allowing a thin planar optical component to be inserted. The results presented here will enable miniaturization and simplification of photonic chips with integrated waveguides by replacing bulk coupling lenses with integrated optical fibers.

Single-peak fiber Bragg gratings in suspended-core optical fibers.

Femtosecond laser inscribed fiber Bragg gratings in pure-silica suspended-core optical fibers have previously been demonstrated as a promising platform for high temperature sensing. However, the density of gratings that could be written on a single fiber was limited by undesired reflections associated with higher order modes in these high numerical aperture fibers. This resulted in a complex, broadband reflection spectrum with limited multiplexing capability. In this work we utilize modifications to the fine structure of the suspended core optical fibers to fine tune the relative confinement loss of the optical fiber modes, thus reducing the contribution from such higher order modes. The effects of these changes on mode propagation are modeled, giving a range of fibers with different confinement loss properties which can be tailored to the specific length scale of a desired application. We achieve single-peak reflections from individual fiber Bragg gratings, significantly improving performance for multipoint sensing and demonstrate this technique by writing 20 gratings onto a single fiber.

Elucidating the mechanism of selective ion adsorption to the liquid water surface.

Adsorption of aqueous thiocyanate ions from bulk solution to the liquid/vapor interface was measured as a function of temperature by resonant UV second harmonic generation spectroscopy. The resulting adsorption enthalpy and entropy changes of this prototypical chaotrope were both determined to be negative. This surprising result is supported by molecular simulations, which clarify the microscopic origins of observed thermodynamic changes. Calculations reveal energetic influences of adsorbed ions on their surroundings to be remarkably local. Negative adsorption enthalpies thus reflect a simple repartitioning of solvent density among surface, bulk, and coordination regions. A different, and much less spatially local, mechanism underlies the concomitant loss of entropy. Simulations indicate that ions at the interface can significantly bias surface height fluctuations even several molecular diameters away, imposing restrictions consistent with the scale of measured and computed adsorption entropies. Based on these results, we expect an ion's position in the Hofmeister lyotropic series to be determined by a combination of driving forces associated with the pinning of capillary waves and with a competition between ion hydration energy and the neat liquid's surface tension.

Adsorption of thiocyanate ions to the dodecanol/water interface characterized by UV second harmonic generation.

Recent experimental and theoretical results have firmly established the existence of enhanced concentrations of selected ions at the air/water interface. Ion adsorption to aqueous interfaces involving complex organic molecules is relevant to biology in connection with the familiar but incompletely understood Hofmeister effects. Here, we describe resonant UV second harmonic generation (SHG) studies of the strongly chaotropic thiocyanate ion adsorbed to the interface formed by water and a monolayer of dodecanol, wherein the Gibbs free energy of adsorption was determined to be -6.7 +/- 1.1 and -6.3 +/- 1.8 kJ/mol for sodium and potassium thiocyanate, respectively, coincident with the value determined for thiocyanate at the air/water interface. Interestingly, near 4 M and higher concentrations, the resonant SHG signal increases discontinuously, indicating a structural change in the interfacial region.

Femtosecond-laser-written Microstructured Waveguides in BK7 Glass.

There is a deficiency of low-loss microstructured waveguides that can be fabricated with a single laser-pass to minimize stress build-up, which can enable enhanced functionality and higher compactness for integrated optical devices. We demonstrate, for the first time, a series of multi-ring claddings each with a pair of cores in BK7 glass. Each waveguide was fabricated using only a single laser-pass at 1 MHz pulse repetition rate, 5 mm/s translation speed, 250 fs pulse width, over a set of pulse energies. We obtained the lowest-reported propagation loss of 0.062 dB/cm, measured at 1155 nm wavelength from the waveguide written with 340 nJ pulse energy. The maximum observed numerical aperture is 0.020, measured at 1155 nm wavelength from the waveguide written with 620 nJ pulse energy. Such waveguides could be incorporated in integrated Raman laser platforms for biomedical applications.