Assessment of the Potential of Electrochemical Steps in Direct Air Capture through Techno-Economic Analysis.

Direct air capture (DAC) technologies are proposed to reduce the atmospheric CO2 concentration to mitigate climate change and simultaneously provide carbon as a feedstock independent of fossil resources. The currently high energy demand and cost of DAC technologies are challenging and could limit the significance of DAC processes. The present work estimates the potential energy demand and the levelized cost of capture (LCOC) of liquid solvent absorption and solid adsorption DAC processes in the long term. A consistent framework is applied to compare nonelectrochemical to electrochemical DAC processes and estimate the LCOC depending on the electricity price. We determine the equivalent cell voltage needed for the electrochemical steps to achieve comparable or lower energy demand than nonelectrochemical processes. The capital expenses (CapEx) of the electrochemical steps are estimated using analogies to processes that are similar in function. The results are calculated for a range of initial data of CapEx and energy demand to include uncertainties in the data.

Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting.

Dye-sensitized photoelectrodes consisting of photosensitizers and molecular catalysts with tunable structures and adjustable energy levels are attractive for low-cost and eco-friendly solar-assisted synthesis of energy rich products. Despite these advantages, dye-sensitized NiO photocathodes suffer from severe electron-hole recombination and facile molecule detachment, limiting photocurrent and stability in photoelectrochemical water-splitting devices. In this work, we develop an efficient and robust biohybrid dye-sensitized NiO photocathode, in which the intermolecular charge transfer is enhanced by a redox polymer. Owing to efficient assisted electron transfer from the dye to the catalyst, the biohybrid NiO photocathode showed a satisfactory photocurrent of 141±17 µA·cm-2 at neutral pH at 0 V versus reversible hydrogen electrode and a stable continuous output within 5 h. This photocathode is capable of driving overall water splitting in combination with a bismuth vanadate photoanode, showing distinguished solar-to-hydrogen efficiency among all reported water-splitting devices based on dye-sensitized photocathodes. These findings demonstrate the opportunity of building green biohybrid systems for artificial synthesis of solar fuels.