1.
Org Lett
; 22(23): 9398-9403, 2020 12 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-33226830
RESUMEN
A silver-mediated internal alkyne-guided fluorination of unactivated C(sp3)-H bonds is described. The reaction provides a facile access to γ-fluorinated fluoroalkylated (Z)-alkenes from readily available alkynes in promising yields with excellent regioselectivity, stereoselectivity, and site selectivity.
2.
Chem Commun (Camb)
; 54(42): 5373-5376, 2018 May 22.
Artículo
en Inglés
| MEDLINE
| ID: mdl-29756622
RESUMEN
A novel photocatalytic acylarylation of unactivated alkenes using diaryliodonium salts as the arylation reagent is described. The reaction produces a variety of 2-benzyl indanones, 3,4-dihydronaphthalen-1(2H)-ones, and 2,3-dihydroquinolin-4(1H)-ones in promising yields with excellent diastereoselectivity under very mild conditions, which may be appealing for the synthesis of biologically active molecules.