RESUMEN
Enhancement of the luminescence efficiency of two new diazapentacenium salts (D1 and D2) of more than 55 for D1 and 22 times for D2) in poor solvents, acetonitrile and/or dichloromethane, was observed and rationalized as formation of emissive J-aggregates. Both compounds displaying 4-n-decylphenyl substituents at the 7,14-carbons and phenyl (D1) or 2,6-difluorophenyl (D2) substituents at the quaternary nitrogen atoms in 5,12-positions have been synthetized in a two-step procedure involving a two-fold Buchwald-Hartwig-type CN cross-coupling and an electrophilic Friedel-Crafts-type cyclization. The optical properties of the dicationic diazapentacenium salts in various solvents and in thin films have been investigated by steady-state and time-resolved absorption and photoluminescence spectroscopies. In thin films and in good solvents, isolated molecules coexist with aggregates. Nonetheless, D1 is seven times more emissive than D2, reflecting a higher J-aggregate contribution in the former.
RESUMEN
Polycationic stepladder polymers containing 5,12-diazapentacenium bistriflate repeat units are made in a two-step sequence of a carbon-nitrogen cross coupling polymerization and subsequent postpolymerization cyclization. The deeply colored products show a rather weak conjugative interaction between the dicationic diazapentacenium repeat units along the polymer chains.