Main Group Pentafulvenes: Challenges and Opportunities in Heavy Main Group Isolobal Substitution of Pentafulvene.

Heterofulvenes based on isolobal substitution of carbon fragments by (heavier) main group motifs provide a rich source of structurally interesting building blocks with electronic situations that can vastly differ from all-carbon congeners. Group 13, heavier 14 & 16 fulvenes are rare and pose significant stability challenges, while group 15 derivatives, particularly phosphorus and arsenic, have led to many derivatives with intriguing opto-electronic properties.