Sustainable Valorization of Bioplastic Waste: A Review on Effective Recycling Routes for the Most Widely Used Biopolymers.

Plastics-based materials have a high carbon footprint, and their disposal is a considerable problem for the environment. Biodegradable bioplastics represent an alternative on which most countries have focused their attention to replace of conventional plastics in various sectors, among which food packaging is the most significant one. The evaluation of the optimal end-of-life process for bioplastic waste is of great importance for their sustainable use. In this review, the advantages and limits of different waste management routes-biodegradation, mechanical recycling and thermal degradation processes-are presented for the most common categories of biopolymers on the market, including starch-based bioplastics, PLA and PBAT. The analysis outlines that starch-based bioplastics, unless blended with other biopolymers, exhibit good biodegradation rates and are suitable for disposal by composting, while PLA and PBAT are incompatible with this process and require alternative strategies. The thermal degradation process is very promising for chemical recycling, enabling building blocks and the recovery of valuable chemicals from bioplastic waste, according to the principles of a sustainable and circular economy. Nevertheless, only a few articles have focused on this recycling process, highlighting the need for research to fully exploit the potentiality of this waste management route.

Waste incineration in rotary kilns: a new simulation combustion tool to support design and technical change.

This article presents a tool based on a simplified model developed for the combustion processes in a rotary kiln incinerator (slightly inclined rotating primary combustion chamber). The model was developed with the aim of supporting the design phase of the incinerator combustion chamber and, at the same time, of investigating possible technical changes in existing plants in order to optimise the combustion process and the dimension of the rotary kiln (length, diameter) as a function of the characteristics of the fed waste. The tool has been applied and the obtained results compared with a real incineration plant operating on healthcare waste located in Rome (Italy). The mass and thermal balances were taken into account, together with kinetic parameters for the combustion of the specific waste stream. The mass balance considered only the major mass components (carbon, hydrogen, oxygen, nitrogen and sulphur). The measured external temperatures appear to be in good agreement with the simulated results. A sensitivity analysis of the plant under different operating conditions was carried out using different input flow rates and excess air ratios, and an assessment was made of the refractory and insulator properties of the kiln's behaviour. Some of the simulated results were used during the periodical maintenance to improve the refractory characteristics in order to reduce the fret and corrosion process.

Spent coffee enhanced biomethane potential via an integrated hydrothermal carbonization-anaerobic digestion process.

This study reports the implications of using spent coffee hydrochar as substrate for anaerobic digestion (AD) processes. Three different spent coffee hydrochars produced at 180, 220 and 250 °C, 1 h residence time, were investigated for their biomethane potential in AD process inoculated with cow manure. Spent coffee hydrochars were characterized in terms of ultimate, proximate and higher heating value (HHV), and their theoretical bio-methane yield evaluated using Boyle-Buswell equation and compared to the experimental values. The results were then analyzed using the modified Gompertz equation to determine the main AD evolution parameters. Different hydrochar properties were related to AD process performances. AD of spent coffee hydrochars produced at 180 °C showed the highest biomethane production rate (46 mL CH4/gVS.d), a biomethane potential of 491 mL/gVS (AD lasting 25 days), and a biomethane gas daily composition of about 70%.