Application of NF Polymeric Membranes for Removal of Multicomponent Heat-Stable Salts (HSS) Ions from Methyl Diethanolamine (MDEA) Solutions.

This study presents an efficient and scalable process for removing the heat-stable salts (HSS) ions from amine solution while recovering methyl diethanolamine (MDEA) solution for its reuse in gas sweetening plants. The presence of HSS in the amine solution causes the loss of solvent capacity, foaming, fouling, and corrosion in gas sweetening units so their removal is crucial for a more well-performing process. Furthermore, the recovery of the amine solution can make the sweetening step a more sustainable process. In this study, for the first time, the removal of a multicomponent mixture of HSS from MDEA solution was investigated via a nanofiltration process using flat-sheet NF-3 membranes. The impact of operating parameters on salts and amine rejection, and flux, including the operating pressure, HSS ions concentration, and MDEA concentration in the feed solution was investigated. Results based on the nanofiltration of an amine stream with the same composition (45 wt.% MDEA solution) as that circulating in a local gas refinery (Ilam Gas refinery), demonstrated a removal efficiency of HSS ions in the range from 75 to 80% and a MDEA rejection of 0% indicating the possibility of reusing this stream in the new step of gas sweetening.

Study on the Separation of H2 from CO2 Using a ZIF-8 Membrane by Molecular Simulation and Maxwell-Stefan Model.

The purification of H2-rich streams using membranes represents an important separation process, particularly important in the viewpoint of pre-combustion CO2 capture. In this study, the separation of H2 from a mixture containing H2 and CO2 using a zeolitic imidazolate framework (ZIF)-8 membrane is proposed from a theoretical point of view. For this purpose, the adsorption and diffusion coefficients of H2 and CO2 were considered by molecular simulation. The adsorption of these gases followed the Langmuir model, and the diffusion coefficient of H2 was much higher than that of CO2. Then, using the Maxwell-Stefan model, the H2 and CO2 permeances and H2/CO2 permselectivities in the H2-CO2 mixtures were evaluated. Despite the fact that adsorption of CO2 was higher than H2, owing to the simultaneous interference of adsorption and diffusion processes in the membrane, H2 permeation was more pronounced than CO2. The modeling results showed that, for a ZIF-8 membrane, the H2/CO2 permselectivity for the H2-CO2 binary mixture 80/20 ranges between 28 and 32 at ambient temperature.

Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution.

The formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane process that ensures the reuse of amine solution for gas sweetening. This model studies the physics of the nanofiltration process by adjusting and investigating pore radius, the effects of membrane charge, and other membrane characteristics. In this paper, the performance of the ternary ions was investigated during the removal process from methyl di-ethanol amine solution by the nanofiltration membrane process. Correlation between feed concentration and permeate concentration, using experimental results with mathematical correlation as Ci,p = f (Ci,f) was used in modeling. The results showed that the calculated data from the model provided a good agreement with experimental results (R2 = 0.90-0.75). Also, the effect of operating conditions (including feed pressure and feed flow rate on ions rejection and recovery ratio across the flat-sheet membrane) was studied. The results showed that the recovery and rejection ratios of the NF membrane depend on the driving pressure across the membrane. While the driving pressure is affected by the feed flow conditions and feed pressure.