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1.
Soft Matter ; 18(19): 3649-3659, 2022 May 18.
Artigo em Inglês | MEDLINE | ID: mdl-35438124

RESUMO

As an essential component of the cytoskeleton, actin filaments play a key role in a variety of cellular physiological activities. To better understand the function of actin filaments, which are a special kind of polymer chain, researchers have started to focus on the Brownian dynamics of polymers. Currently, to study the dynamics of polymers, classical explicit bead-spring models and finite-element methods (FEMs) have both been broadly used. However, compared to bead-spring models, FEMs can address the mechanical properties of actin filaments and actin networks with more detail and better accuracy. However, current FEMs do not consider the dynamic assembly of actin into an actin filament network. Here, we extend the traditional FEM and present a new framework of the FEM based on the co-rotational grid method, which allows us to simulate the dynamic growth and branching of actin filaments. Several examples are studied. The proposed numerical model is capable of capturing the dynamic assembly of actin filaments.


Assuntos
Citoesqueleto de Actina , Actinas , Citoesqueleto de Actina/metabolismo , Actinas/metabolismo , Citoesqueleto/metabolismo , Microtúbulos/metabolismo , Simulação de Dinâmica Molecular
2.
J Hazard Mater ; 472: 134472, 2024 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-38696964

RESUMO

Spent ternary lithium-ion batteries contain abundant lithium resource, and their proper disposal is conducive to environmental protection and the comprehensive utilization of resources. Separating valuable metals in the ternary leaching solution is the key to ensuring resource recovery. However, the traditional post-lithium extraction strategies, which heavily rely on ion exchange to remove transition metal ions in the leachate, encounter challenges in achieving satisfactory lithium yields and purities. Based on this, this paper proposed a new strategy to prioritize lithium extraction from ternary leachate using "(+) LiFePO4/FePO4 (-)" lithium extraction system. The preferential recovery of lithium can be realized by controlling the potential over 0.1 V versus Standard Hydrogen Electrode (SHE) without introducing any impurity ions. The lithium recovery rate reaches 98.91%, while the rejection rate of transition ions exceeds 99%, and the separation coefficients of lithium to transition metal ions can reach 126. Notably, the resulting lithium-rich liquid can directly prepare lithium carbonate with a purity of 99.36%. It provides a green and efficient strategy for the preferential recovery of lithium from the spent ternary leachate.

3.
Glob Chall ; 2(2): 1700079, 2018 Feb 09.
Artigo em Inglês | MEDLINE | ID: mdl-31565321

RESUMO

Lithium extraction from high Mg/Li ratio brine is a key technical problem in the world. Based on the principle of rocking-chair lithium-ion batteries, cathode material LiFePO4 is applied to extract lithium from brine, and a novel lithium-ion battery system of LiFePO4 | NaCl solution | anion-exchange membrane | brine | FePO4 is constructed. In this method, Li+ is selectively absorbed from the brine by FePO4 (Li+ + e + FePO4 = LiFePO4); meanwhile, Li+ is desorbed from LiFePO4 (LiFePO4 - e = Li+ + FePO4) and enriched efficiently. To treat a raw brine solution, the Mg/Li ratio decreases from the initial 134.4 in the brine to 1.2 in the obtained anolyte and 83% lithium is extracted. For the treatment of an old brine solution, the Mg/Li ratio decreases from the initial 48.4 in the brine to 0.5 and the concentration of lithium in the anolyte is accumulated about six times (from the initial 0.51 g L-1 in the brine to 3.2 g L-1 in the anolyte), with the absorption capacity of about 25 mg (Li) g (LiFePO4)-1. Additionally, it displays a great perspective on the application in light of its high selectively, good cycling performance, effective lithium enrichment, environmental friendliness, low cost, and avoidance of poisonous organic reagents and harmful acid or oxidant.

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