1.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 7): m819, 2009 Jun 24.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21582741
RESUMO
The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra-molecular hydrogen bonds between the exo-NH(2) group H atoms and acetyl-acetonate O atoms stabilize the crystal structure.