1.
RSC Adv
; 8(52): 29924-29927, 2018 Aug 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35547277
RESUMO
The oxidation of Hantzsch ester by a pyrylium cation takes place via electron-proton-electron transfer. The reaction was investigated with EPR spectroscopy using TEMPO and DMPO for inhibition and spin trapping, respectively, of the radicals appearing during the reaction. The present in-depth EPR study of the radical reactions of a NADH analogue indicate a complex electron transfer mechanism in the title reaction.