A ferroelectric fin diode for robust non-volatile memory.

Among today's nonvolatile memories, ferroelectric-based capacitors, tunnel junctions and field-effect transistors (FET) are already industrially integrated and/or intensively investigated to improve their performances. Concurrently, because of the tremendous development of artificial intelligence and big-data issues, there is an urgent need to realize high-density crossbar arrays, a prerequisite for the future of memories and emerging computing algorithms. Here, a two-terminal ferroelectric fin diode (FFD) in which a ferroelectric capacitor and a fin-like semiconductor channel are combined to share both top and bottom electrodes is designed. Such a device not only shows both digital and analog memory functionalities but is also robust and universal as it works using two very different ferroelectric materials. When compared to all current nonvolatile memories, it cumulatively demonstrates an endurance up to 1010 cycles, an ON/OFF ratio of ~102, a feature size of 30 nm, an operating energy of ~20 fJ and an operation speed of 100 ns. Beyond these superior performances, the simple two-terminal structure and their self-rectifying ratio of ~ 104 permit to consider them as new electronic building blocks for designing passive crossbar arrays which are crucial for the future in-memory computing.

Hardware implementation of photoelectrically modulated dendritic arithmetic and spike-timing-dependent plasticity enabled by an ion-coupling gate-tunable vertical 0D-perovskite/2D-MoS2 hybrid-dimensional van der Waals heterostructure.

Brain-inspired nanodevices have been demonstrated to possess outstanding characteristics for implementing neuromorphic computing. Among these devices, photoelectrically modulated neuromorphic transistors are regarded as the basic building blocks for applications in emerging brain-like devices. However, to date, efficient optoelectronic-hybrid neuromorphic devices are still lacking. Because conventional transistors based on mono-semiconductor materials cannot absorb adequate light to ensure efficient light-matter interactions, they pose significant challenges to the synchronous processing of photoelectric information. Here, a novel photoelectrically modulated neuromorphic device based on an ion-coupling gate-tunable vertical 0D-CsPbBr3-quantum-dots/2D-MoS2 hybrid-dimensional van der Waals heterojunction is demonstrated by using a polymer ion gel electrolyte as the gate dielectric. A super-efficient heterojunction interface for photo-carrier transport is developed by integrating CsPbBr3 quantum dots with 2D-layered MoS2 semiconductors. We experimentally demonstrate that the drain-source current can be modulated by applying spikes to the drain and gate terminals, and the conductance can also be tuned by external light stimulus. Most importantly, photoelectrically modulated spiking Boolean logics, dendritic integrations in both temporal and spatial modes, and Hebbian learning rules can be successfully mimicked in our proposed hybrid-dimensional device using this intriguing optical and electrical synergy approach. These results suggest that the proposed device has great potential in intelligent cognitive systems and neuromorphic computing applications.