Dielectric Study of Tetraalkylammonium and Tetraalkylphosphonium Levulinate Ionic Liquids.

Broadband dielectric spectroscopy in a broad temperature range was employed to study ionic conductivity and dynamics in tetraalkylammonium- and tetraalkylphosphonium-based ionic liquids (ILs) having levulinate as a common anion. Combining data for ionic conductivity with data obtained for viscosity in a Walden plot, we show that ionic conductivity is controlled by viscosity while a strong association of ions takes place. Higher values for ionic conductivities in a broad temperature range were found for the tetraalkylphosphonium-based IL compared to its ammonium homolog in accordance with its lower viscosity. Levulinate used in the present study as anion was found to interact and associate stronger with the cations forming ion-pairs or other complexes compared to the NTf2 anion studied in literature. In order to analyze dielectric data, different fitting approaches were employed. The original random barrier model cannot well describe the conductivity especially at the higher frequencies region. In electric modulus representation, two overlapping mechanisms contribute to the broad low frequencies peak. The slower process is related to the conduction mechanism and the faster to the main polarization process of the complex dielectric permittivity representation. The correlation of the characteristic time scales of the previous relaxation processes was discussed in terms of ionic interactions.

Non-Extensive Statistical Analysis of Acoustic Emissions: The Variability of Entropic Index q during Loading of Brittle Materials until Fracture.

Non-extensive statistical mechanics (NESM), introduced by Tsallis based on the principle of non-additive entropy, is a generalisation of the Boltzmann-Gibbs statistics. NESM has been shown to provide the necessary theoretical and analytical implementation for studying complex systems such as the fracture mechanisms and crack evolution processes that occur in mechanically loaded specimens of brittle materials. In the current work, acoustic emission (AE) data recorded when marble and cement mortar specimens were subjected to three distinct loading protocols until fracture, are discussed in the context of NESM. The NESM analysis showed that the cumulative distribution functions of the AE interevent times (i.e., the time interval between successive AE hits) follow a q-exponential function. For each examined specimen, the corresponding Tsallis entropic q-indices and the parameters ßq and τq were calculated. The entropic index q shows a systematic behaviour strongly related to the various stages of the implemented loading protocols for all the examined specimens. Results seem to support the idea of using the entropic index q as a potential pre-failure indicator for the impending catastrophic fracture of the mechanically loaded specimens.

Non-Extensive Statistical Analysis of Acoustic Emissions Recorded in Marble and Cement Mortar Specimens Under Mechanical Load Until Fracture.

Non-extensive statistical mechanics (NESM), which is a generalization of the traditional Boltzmann-Gibbs statistics, constitutes a theoretical and analytical tool for investigating the irreversible damage evolution processes and fracture mechanisms occurring when materials are subjected to mechanical loading. In this study, NESM is used for the analysis of the acoustic emission (AE) events recorded when marble and cement mortar specimens were subjected to mechanical loading until fracture. In total, AE data originating from four distinct loading protocols are presented. The cumulative distribution of inter-event times (time interval between two consecutive AE events) and the inter-event distances (three-dimensional Euclidian distance between the centers of successive AE events) were examined under the above concept and it was found that NESM is suitable to detect criticality under the terms of mechanical status of a material. This was conducted by evaluating the fitting results of the q-exponential function and the corresponding q-indices of Tsallis entropy qδτ and qδr, along with the parameters τδτ and dδr. Results support that qδτ+qδr≈2 for AE data recorded from marble and cement mortar specimens of this work, which is in good agreement with the conjecture previously found in seismological data and AE data recorded from Basalt specimens.

Revealing the Proximity of Concrete Specimens to Their Critical Damage Level by Exploring the Cumulative Counts of the Acoustic Emissions in the Natural Time Domain.

This study aims to explore the possibility of detecting indices that could potentially provide warning about the proximity of internal damage to critical levels, beyond which catastrophic fracture is impending. In this direction, advantage was taken of the Cumulative Counts that were recorded during the mechanical loading of specimens made of either plain or fiber-reinforced concrete. The parameter adopted for the analysis was the average rate of change in the Cumulative Counts. Τhe evolution of the specific parameter was considered in the Natural Time Domain, rather than in the conventional time domain. Experimental data from already published three-point bending protocols were used. It was revealed that the specific parameter attains, systematically, a limiting value equal to unity exactly at the instant at which the load reaches its maximum value, which is not identical to the load recorded at the instant of fracture. Similar observations were made for a complementary protocol with uniaxially compressed mortar specimens. The conclusions drawn were supported by the b-values analysis of the respective acoustic data, again in terms of Natural Time. It is, thus, indicated that the evolution of the average rate of change in the Cumulative Counts in the Natural Time Domain provides an index about the proximity of the applied load to a value beyond which the specimen enters into the critical state of impending fracture.

Remote and In-Person Learning: Utility Versus Social Experience.

The massive transition from in-person to remote teaching increased the impact of technology on the everyday life of the universities. Without the face-to-face component, learning and teaching became a completely different experience for students and teachers. Recording the attitudes and perceptions of the undergraduate students on the new situation became necessary for the faculties to support them effectively. This research collected quantitative and qualitative data from 336 students of all the years of studies. The students preferred in-person teaching and reported higher engagement, learning, and understanding during classroom teaching. More senior students, who had developed face-to-face ties with their colleagues before the pandemic, found it easier to continue their interactions remotely. They were interested in matching learning with the duties and needs at the particular period of their life, despite their beliefs concerning the effectiveness of in-person teaching. The first-year students found it challenging to develop relationships remotely, and they were the most frustrated. Overall, students in the first years of their studies perceived remote teaching as dissatisfactory compared to the more senior students. Similar to other publications, the respondents of this study challenged the effectiveness of remote teaching and the concomitant transition from in-person to remote social relationships.

Spatio-Temporal Distribution of the Sources of Acoustic Events in Notched Fiber-Reinforced Concrete Beams under Three-Point Bending.

The acoustic activity, generated in notched, beam-shaped concrete specimens, loaded under three-point bending, is studied in terms of the position of the sources of acoustic events, and the frequency of their generation. Both plain specimens (without any internal reinforcement) and specimens reinforced with various types of short fibers were tested. The target of the study is to investigate the existence of indices that could be considered as pre-failure indicators of the upcoming fracture. In addition, an attempt is undertaken to classify the damage mechanisms activated to tensile or shear nature. Considering comparatively the spatio-temporal evolution of the position of the acoustic sources and the respective temporal evolution of the frequency of generation of acoustic events, it was concluded that for relatively low load levels the acoustic sources are rather randomly distributed all over the volume of the specimens. As the load increases toward its maximum value, the acoustic sources tend to accumulate in the immediate vicinity of the crown of the notch and the average distance between them approaches a minimum value. When this minimum value is attained, the load is maximized and the generation frequency of the acoustic events increases rapidly. The simultaneous fulfillment of these three conditions is observed a few seconds before the onset of propagation of the catastrophic macrocrack for all classes of specimens tested, providing a kind of warning signal about the upcoming fracture. Moreover, the classification of the damage mechanisms to tensile and shear ones revealed a crucial difference between the plain and the reinforced specimens after the maximization of the load applied. Indeed, while for the plain specimens, the prevailing damage mechanism is tensile microcracking, for the reinforced specimens a balance between tensile and shear damage mechanisms is observed after the load applied has attained its peak and starts decreasing.

Electrical Methods for Sensing Damage in Cement Mortar Beams Combined with Acoustic Emissions.

The temporal variation in terms of the "time-to-failure" parameter of the recordings of the electrical resistance and the acoustic emissions from concurrent measurements in three cement mortar specimens of prismatic shape that were subjected to a three-point bending test until fracture are studied. The novelty of the work at hand lies in the demonstration that the electrical resistance is described by a power law during the last stages of the loading protocols. The onset of the validity of the power law is indicative of the specimens' imminent fracture, thus providing a useful pre-failure indicator. The above findings are supported by the analysis of the recorded acoustic signals in terms of the F-function and the Ib-value formulations.