From a bouncing compound drop to a double emulsion.

We show that a double emulsion (oil in water in oil) can be created starting from a compound droplet (surfactant solution in oil). The compound drop bounces on a vertically vibrated liquid surface. When the amplitude of the vibration exceeds a threshold value, the oil layer penetrates the water content and leaves a tiny oil droplet within. As this phenomenon occurs at each vigorous impact, the compound drop progressively transforms into a double emulsion. The emulsification threshold, which is observed to depend on the forcing frequency but not on the drop size, is rationalized by investigating the impact of compound drops onto a static liquid surface. The droplet creation occurs when the kinetic energy released at impact is larger than the energy required to deform the compound drop, namely when the Weber number is higher than a given threshold value.

Droplets sliding on fibres.

We present the results of a combined experimental and theoretical investigation of oil droplets sliding on fibres. First, both the axisymmetric shape and the motion of a droplet on a vertical fibre are described. The motion is shown to result from a balance between the droplet weight and the viscous stresses. On a long-term range, the droplet loses some mass through coating the fibre, which decreases its velocity. In a second time, we rationalize the behaviour of a droplet that encounters a junction between vertical and horizontal fibres. Depending on its size, the droplet may cross the junction or remain blocked. The transition is well described by an ordinary differential equation equivalent to a damped harmonic oscillator truncated to the neighbourhood of the horizontal fibre. This simple system is the basic element for more complex fiber networks that would be useful in microfluidic applications involving droplets.

Lifetime of a bouncing droplet.

When a droplet is gently laid onto the surface of the same liquid, it stays at rest for a moment before coalescence. The coalescence can be delayed and sometimes inhibited by injecting fresh air under the droplet. This can happen when the surface of the bath oscillates vertically. In this case the droplet basically bounces on the interface. The lifetime of the droplet has been studied with respect to the amplitude and the frequency of the excitation. The lifetime decreases when the acceleration increases. The thickness of the air film between the droplet and the bath has been investigated using interference fringes obtained when the system is illuminated by low-pressure sodium lamps. Moreover, both the shape evolution and the motion of the droplet center of mass have been recorded in order to evidence the phase offset between the deformation and the trajectory. A short lifetime is correlated to a small air-film thickness and to a large phase offset between the maximum of deformation and the minimum of the vertical position of the center of mass.

Bouncing of polymeric droplets on liquid interfaces.

The effect of polymers on the bouncing behavior of droplets in a highly viscous, vertically shaken silicone oil bath was investigated in this study. Droplets of a sample liquid were carefully placed on a vibrating bath that was maintained well below the threshold of Faraday waves. The bouncing threshold of the plate acceleration depended on the acceleration frequency. For pure water droplets and droplets of aqueous polymer solutions, a minimum acceleration amplitude was observed in the acceleration threshold curves as a function of frequency. The bouncing acceleration amplitude for a droplet of a dilute aqueous polymer solution was higher than the acceleration amplitude for a pure water droplet. Measurements of the center of mass trajectory and the droplet deformations showed that the controlling parameter in the bouncing process was the oscillating elongational rate of the droplet. This parameter can be directly related to the elongational viscosity of the polymeric samples. The large elongational viscosity of the polymer solution droplets suppressed large droplet deformations, resulting in less chaotic bouncing.

Symmetry breaking in a few-body system with magnetocapillary interactions.

We have experimentally investigated the interactions between floating magnetic spheres which are submitted to a vertical magnetic field, ensuring a tunable repulsion, while capillary forces induce attraction. We emphasize the complex arrangements of floating bodies. The equilibrium distance between particles exhibits hysteresis when the applied magnetic field is modified. Irreversible processes are evidenced. Symmetry breaking is also found for three identical floating bodies when the strength of the magnetic repulsion is tuned. We propose a Dejarguin-Landau-Verwey-Overbeek (DLVO)-like potential, i.e., an interaction potential with a primary and a secondary minimum, capturing the main physical features of the magnetocapillary interaction, which is relevant for self-assembly.

Impact of liquid droplets on granular media.

The crater formation due to the impact of a water droplet onto a granular bed has been experimentally investigated. Three parameters were tuned: the impact velocity, the size of the droplet, and the size of the grains. The aim is to determine the influence of the kinetic energy on the droplet pattern. The shape of the crater depends on the kinetic energy at the moment the droplet starts to impact the bed. The spreading and recession of the liquid during the impact were carefully analyzed from the dynamical point of view, using image analysis of high-speed video recordings. The different observed regimes are characterized by the balance between the impregnation time of the water by the granular bed by the water and the capillary time responsible for the recession of the drop.

Hysteretic behavior in three-dimensional soap film rearrangements.

We report experiments on soap film configurations in a triangular prism for which the shape factor can be changed continuously. Two stable configurations can be observed for a range of the shape factor h, being the prism-height/edge-length ratio. A hysteretic behavior is found, due to the occurrence of another local minima in the free energy. Contrary to a common belief, soap films can be trapped in a particular configuration being different from a global surface minimization. This metastability can be evidenced from a geometrical model based on idealized structures. Depending on the configuration, the transition is either first or second order, providing clues on the structural relaxations taking place into three-dimensional foams, such as T1 rearrangements.

Dynamics of a bouncing droplet onto a vertically vibrated interface.

Low viscosity (<100 cSt) silicon oil droplets are placed on a high viscosity (1000 cSt) oil bath that vibrates vertically. The viscosity difference ensures that the droplet is more deformed than the bath interface. Droplets bounce periodically on the bath when the acceleration of its sinusoidal motion is larger than a threshold value. The threshold is minimum for a particular frequency of excitation: droplet and bath motions are in resonance. The bouncing droplet has been modeled by considering the deformation of the droplet and the lubrication force exerted by the air layer between the droplet and the bath. Threshold values are predicted and found to be in good agreement with our measurements.