A high-pressure resistant ternary network hydrogel based flexible strain sensor with a uniaxially oriented porous structure toward gait detection.

Gait abnormalities have been widely investigated in the diagnosis and treatment of neurodegenerative diseases. However, it is still a great challenge to achieve a comfortable, convenient, sensitive and high-pressure resistant flexible gait detection sensor for real-time health monitoring. In this work, a polyaniline (PANI)@(polyacrylic acid (PAA)-polyvinyl alcohol (PVA)) (PANI@(PVA-PAA)) ternary network hydrogel with a uniaxially oriented porous featured structure was successfully prepared using a simple freeze-thaw method and in situ polymerization. The PANI@(PVA-PAA) hydrogel shows excellent compressive mechanical properties (423.44 kPa), favorable conductivity (2.02 S m-1) and remarkable durability (500 loading-unloading cycle), and can sensitively detect the effect of pressure with a fast response time (200 ms). The PANI@(PVA-PAA) hydrogel assembled into a flexible sensor can effectively identify the movement state of the shoulder, knee and even the sole of the plantar for gait detection. The uniaxially oriented porous structure enables the hydrogel-based sensor to have a high rate of change in the longitudinal direction and can effectively distinguish various gaits. The construction of a hydrogen bond between PANI and the PVA-PAA hydrogel ensures the uniform distribution of PANI in the hydrogel to form a ternary network structure, which improves the pressure resistance and conductivity of the PANI@(PVA-PAA) hydrogel. Thus, PANI@(PVA-PAA) hydrogel flexible sensor for gait detection can not only effectively monitor some serious diseases but also detect some unscientific exercise in people's daily life.

Research on the Improvement of Concrete Autogenous Self-healing Based on the Regulation of Cement Particle Size Distribution (PSD).

Overgrinding of Portland cement brings excessive shrinkage and poor self-healing ability to concrete. In this paper, through the ultrasonic test and optical micrograph observation, the self-healing properties of concrete prepared by cement with different particle size distributions were studied. Besides, the effect of carbonation and continued hydration on self-healing of concrete was analyzed. Results show that, for the Portland cement containing more particles with the size 30~60 µm, the concrete could achieve a better self-healing ability of concrete at 28 days. For the two methods to characterize the self-healing properties of concrete, the ultrasonic test is more accurate in characterizing the self-healing of internal crack than optical micrograph observation. The autogenous self-healing of concrete is jointly affected by the continued hydration and carbonation. At 7 days and 30 days, the autogenous self-healing of concrete is mainly controlled by the continued hydration and carbonation, respectively. The cement particle size could affect the continued hydration by affecting un-hydrated cement content and the carbonation by affecting the Ca(OH)2 content. Therefore, a proper distribution of cement particle size, which brings a suitable amount of Ca(OH)2 and un-hydrated cement, could improve the self-healing ability of concrete.