Development of Bronze Phase Titanium Dioxide Nanorods for Use as Fast-Charging Anode Materials in Lithium-Ion Batteries.

Bronze phase titanium dioxide (TiO2(B)) nanorods were successfully prepared via a hydrothermal method together with an ion exchange process and calcination by using anatase titanium dioxide precursors in the alkali hydrothermal system. TiO2 precursors promoted the elongation of nanorod morphology. The different hydrothermal temperatures and reaction times demonstrated that the synthesis parameters had a significant influence on phase formation and physical morphologies during the fabrication process. The effects of the synthesis conditions on the tailoring of the crystal morphology were discussed. The growth direction of the TiO2(B) nanorods was investigated by X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The as-synthesized TiO2(B) nanorods obtained after calcination were used as anode materials and tested the efficiency of Li-ion batteries. This research will study the effects of particle morphologies and crystallinity of TiO2(B) derived from a modified hydrothermal method on the capacity and charging rate of the Li-ion battery. The TiO2(B) nanorods, which were synthesized by using a hydrothermal temperature of 220 °C for 12 h, presented excellent electrochemical performance with the highest Li storage capacity (348.8 mAh/g for 100 cycles at a current density of 100 mA/g) and excellent high-rate cycling capability (a specific capacity of 207.3 mAh/g for 1000 cycles at a rate of 5000 mA/g).

Fast-Charging Anode Materials and Novel Nanocomposite Design of Rice Husk-Derived SiO2 and Sn Nanoparticles Self-Assembled on TiO2(B) Nanorods for Lithium-Ion Storage Applications.

A novel microstructure of anode materials for lithium-ion batteries with ternary components, comprising tin (Sn), rice husk-derived silica (SiO2), and bronze-titanium dioxide (TiO2(B)), has been developed. The goal of this research is to utilize the nanocomposite design of rice husk-derived SiO2 and Sn nanoparticles self-assembled on TiO2(B) nanorods, Sn-SiO2@TiO2(B), through simple chemical route methods. Following that, the microstructure and electrochemical performance of as-prepared products were investigated. The major patterns of the X-ray diffraction technique can be precisely indexed as monoclinic TiO2(B). The patterns of SiO2 and Sn were found to be low in intensity since the particles were amorphous and in the nanoscale range, respectively. Small spherical particles, Sn and SiO2, attached to TiO2(B) nanorods were discovered. Therefore, the influence mechanism of Sn-SiO2@TiO2(B) fabrication was proposed. The Sn-SiO2@TiO2(B) anode material performed exceptionally well in terms of electrochemical and battery performance. The as-prepared electrode demonstrated outstanding stability over 500 cycles, with a high discharge capacity of ∼150 mA h g-1 at a fast-charging current of 5000 mA g-1 and a low internal resistance of around 250.0 Ω. The synthesized Sn-SiO2@TiO2(B) nanocomposites have a distinct structure, the potential for fast charging, safety in use, and good stability, indicating their use as promising and effective anode materials in better power batteries for the next-generation applications.