A Single-Step Bottom-up Approach for Synthesis of Highly Uniform Mie-Resonant Crystalline Semiconductor Particles at Visible Wavelengths.

Optically Mie-resonant crystalline silicon nanoparticles have long attracted interest for their unique scattering behaviors. Here, we report a bottom-up nonthermal plasma process that produces highly monodisperse particles, with diameters controllable between 60 and 214 nm, by temporarily electrostatically trapping nanoparticles inside a continuous-flow plasma reactor. The particle size is tuned by adjusting the gas residence time in the reactor. By dispersing the nanoparticles in water, optical extinction measurements indicate colloidal solutions of a particle-based metafluid in which particles support both strong magnetic and electric dipole resonances at visible wavelengths. The spectral overlap of the electric and magnetic resonances gives rise to directional Kerker scattering. The extinction measurements show excellent agreement with Mie theory, supporting the idea that the fabrication process enables particles with narrow distributions in size, shape, and composition. This single-step gas-phase process can also produce Mie-resonant nanoparticles of dielectric materials other than silicon and directly deposit them on the desired substrates.

Huygens' Metasurfaces Enabled by Magnetic Dipole Resonance Tuning in Split Dielectric Nanoresonators.

Dielectric metasurfaces that exploit the different Mie resonances of nanoscale dielectric resonators are a powerful platform for manipulating electromagnetic fields and can provide novel optical behavior. In this work, we experimentally demonstrate independent tuning of the magnetic dipole resonances relative to the electric dipole resonances of split dielectric resonators (SDRs). By increasing the split dimension, we observe a blue shift of the magnetic dipole resonance toward the electric dipole resonance. Therefore, SDRs provide the ability to directly control the interaction between the two dipole resonances within the same resonator. For example, we achieve the first Kerker condition by spectrally overlapping the electric and magnetic dipole resonances and observe significantly suppressed backward scattering. Moreover, we show that a single SDR can be used as an optical nanoantenna that provides strong unidirectional emission from an electric dipole source.

Printing Beyond sRGB Color Gamut by Mimicking Silicon Nanostructures in Free-Space.

Localized optical resonances in metallic nanostructures have been increasingly used in color printing, demonstrating unprecedented resolution but limited in color gamut. Here, we introduce a new nanostructure design, which broadens the gamut while retaining print resolution. Instead of metals, silicon nanostructures that exhibit localized magnetic and electric dipole resonances were fabricated on a silicon substrate coated with a Si3N4 index matching layer. Index matching allows a suppression of substrate effects, thus enabling Kerker's conditions to be met, that is, sharpened transitions in the reflectance spectra leading to saturated colors. This nanostructure design achieves a color gamut superior to sRGB, and is compatible with CMOS processes. The presented design could enable compact high-resolution color displays and filters, and the use of a Si3N4 antireflection coating can be readily extended to designs with nanostructures fabricated using other high-index materials.

Unidirectional Meta-Emitters Based on the Kerker Condition Assembled by DNA Origami.

Optical quantum emitters near nanostructures have access to additional relaxation channels and thus exhibit structure-dependent emission properties, including quantum yield and emission directionality. A well-engineered quantum emitter-plasmonic nanostructure hybrid can be considered as an optical meta-emitter consisting of a transmitting nanoantenna driven by an optical-frequency generator. In this work, the DNA origami fabrication method is used to construct ultracompact unidirectional meta-emitters composed of a plasmonic trimer nanoantenna driven by a single dye molecule. The origami is designed to bring the dye to the gap to simultaneously excite the electric and magnetic dipole modes of the trimer nanoantenna. The interference of these modes fulfills the Kerker condition at the fluorophore's emission band, enabling unidirectional emission. We report unidirectional emission from a single molecule with a front-to-back ratio of up to 10.7 dB accompanied by a maximum emission enhancement of 23-fold.

Beyond Conventional Sensing: Hybrid Plasmonic Metasurfaces and Bound States in the Continuum.

Fano resonances result from the strong coupling and interference between a broad background state and a narrow, almost discrete state, leading to the emergence of asymmetric scattering spectral profiles. Under certain conditions, Fano resonances can experience a collapse of their width due to the destructive interference of strongly coupled modes, resulting in the formation of bound states in the continuum (BIC). In such cases, the modes are simultaneously localized in the nanostructure and coexist with radiating waves, leading to an increase in the quality factor, which is virtually unlimited. In this work, we report on the design of a layered hybrid plasmonic-dielectric metasurface that facilitates strong mode coupling and the formation of BIC, resulting in resonances with a high quality factor. We demonstrate the possibility of controlling Fano resonances and tuning Rabi splitting using the nanoantenna dimensions. We also experimentally demonstrate the generalized Kerker effect in a binary arrangement of silicon nanodisks, which allows for the tuning of the collective modes and creates new photonic functionalities and improved sensing capabilities. Our findings have promising implications for developing plasmonic sensors that leverage strong light-matter interactions in hybrid metasurfaces.

Ideal Kerker scattering by homogeneous spheres: the role of gain or loss.

We investigate how the optical gain or loss (characterized by isotropic complex refractive indexes) influence the ideal Kerker scattering of exactly zero backward scattering. It was previously shown that, for non-magnetic homogeneous spheres with incident plane waves, either gain or loss prohibit ideal Kerker scattering, provided that only electric and magnetic multipoles of a specific order are present and contributions from other multipoles can all be made precisely zero. Here we reveal that, when two multipoles of a fixed order are perfectly matched in terms of both phase and magnitude, multipoles of at least the next two orders cannot possibly be tuned to be all precisely zero or even perfectly matched, and consequently cannot directly produce ideal Kerker scattering. Moreover, we further demonstrate that, when multipoles of different orders are simultaneously taken into consideration, loss or gain can serve as helpful rather than harmful contributing factors, for the elimination of backward scattering.

High-Performance Asymmetric Optical Transmission Based on a Dielectric-Metal Metasurface.

Asymmetric optical transmission plays a key role in many optical systems. In this work, we propose and numerically demonstrate a dielectric-metal metasurface that can achieve high-performance asymmetric transmission for linearly polarized light in the near-infrared region. Most notably, it supports a forward transmittance peak (with a transmittance of 0.70) and a backward transmittance dip (with a transmittance of 0.07) at the same wavelength of 922 nm, which significantly enhances operation bandwidth and the contrast ratio between forward and backward transmittances. Mechanism analyses reveal that the forward transmittance peak is caused by the unidirectional excitation of surface plasmon polaritons and the first Kerker condition, whereas the backward transmittance dip is due to reflection from the metal film and a strong toroidal dipole response. Our work provides an alternative and simple way to obtain high-performance asymmetric transmission devices.