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1.
Crit Rev Biotechnol ; 44(7): 1296-1324, 2024 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-38105487

RESUMO

Microalgae have long been regarded as a promising solution for biological carbon abatement from the power industry, offering renewable biomass without competing for land or water resources used for food crops. In this study, we extensively examined the application of photosynthetic microorganisms for closing carbon, nitrogen, and micronutrient loops in the power industry. Subsequently, we explored the bottom-up integration of algal biorefineries into power industry waste streams for increased economic benefits and reduced environmental impacts. Analysis of the available data indicated that microalgae integration with the power industry is primarily performed using flue-gas-assisted cultivation. This approach allows for carbon sequestration typically below one gram per liter per day, too low to significantly impact carbon abatement at achievable scales of microalgae cultivation. Alternative approaches are also being explored. For example, soluble bicarbonate platforms allow for higher biomass productivity and temporary carbon storage. Meanwhile, the use of ashes and waste heat and thermophilic strains can result in lower cultivation costs and better control of cultivation conditions. These approaches offer further incremental improvement to microalgae-based carbon abatement systems in the power industry but are unlikely to be an umbrella solution for carbon reduction. Consequently, in the near term, microalgae-based carbon valorization systems are likely to be limited to niche applications involving the synthesis of high-value products. For microalgae to truly transform carbon abatement processes radical improvements in both biology and engineering approaches are urgently needed.


Assuntos
Resíduos Industriais , Microalgas , Microalgas/metabolismo , Microalgas/crescimento & desenvolvimento , Biomassa , Carbono/metabolismo , Centrais Elétricas , Gerenciamento de Resíduos/métodos
2.
Environ Sci Technol ; 58(40): 17766-17776, 2024 Oct 08.
Artigo em Inglês | MEDLINE | ID: mdl-39315852

RESUMO

Pyrogenic carbon is considered an enhancer to H2-yielding dark fermentation (DF), but little is known about how it regulates extracellular electron transfer (EET) and influences transmembrane respiratory chains and intracellular metabolisms. This study addressed these knowledge gaps and demonstrated that wood waste pyrogenic carbon (biochar) could significantly improve the DF performance; e.g., addition of pyrogenic carbon produced by pyrolysis at 800 °C (PC800) increased H2 yield by 369.7%. Biochemical quantification, electrochemical analysis, and electron respiratory chain inhibition tests revealed that PC800 promoted the extracellular flavin-based electron transfer process and further activated the acceleration of the transmembrane electron transfer. Comparative metagenome/metatranscriptome analyses indicated that the flavin-containing Rnf complex was the potential transmembrane respiratory enzyme associated with PC800-mediated EET. Based on NADH/NAD+ circulation, the promoted Rnf complex could stimulate the functions of the electron bifurcating Etf/Bcd complex and startup of glycolysis. The promoted Etf/Bcd could further contribute to balance the NADH/NAD+ level for glycolytic reactions and meanwhile provide reduced ferredoxin for group A1 [FeFe]-hydrogenases. This proton-energy-linked mechanism could achieve coupling production of ATP and H2. This study verified the important roles of pyrogenic carbon in mediating EET and transmembrane/intracellular pathways and revealed the crucial roles of electron bifurcation in DF for hydrogen production.


Assuntos
Fermentação , Hidrogênio , Transporte de Elétrons , Hidrogênio/metabolismo , Carbono/metabolismo , Flavinas/metabolismo , Elétrons
3.
Environ Res ; 242: 117735, 2024 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-38000630

RESUMO

Biogas methanation emerges as a prominent technology for converting biogas into biomethane in a single step. Furthermore, this technology can be implemented at biogas plant locations, supporting local economies and reducing dependence on large energy producers. However, there is a lack of comprehensive studies on biogas methanation, particularly regarding the technical optimization of operational parameters and the profitability analysis of the overall process. To address this gap, our study represents a seminal work on the technical optimization of biogas methanation obtaining an empirical model to predict the performance of biogas methanation. We investigate the influence of operational parameters, such as reaction temperature, H2/CO2 ratio, space velocity, and CO2 share in the biogas stream through an experimental design. Based on previous research we selected a nickel supported on ceria-alumina catalyst; being nickel a benchmark system for methanation process such selection permits a reliable data extrapolation to commercial units. We showcase the remarkable impact of studied key operation parameters, being the temperature, the most critical factor affecting the reaction performance (ca. 2 to 5 times higher than the second most influencing parameter). The impact of the H2/CO2 ratio is also noticeable. The response surfaces and contour maps suggest that a temperature between 350 and 450 °C and an H2/CO2 ratio between 2.5 and 3.2 optimize the reaction performance. Further experimental tests were performed for model validation and optimization leading to a reliable predictive model. Overall, this study provides validated equations for technology scaling-up and techno-economic analysis, thus representing a step ahead towards real-world applications for bio-methane production.


Assuntos
Biocombustíveis , Dióxido de Carbono , Níquel , Óxido de Alumínio , Biomassa
4.
Environ Res ; 251(Pt 2): 118669, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38499221

RESUMO

In India, majority of the generated municipal solid waste (MSW) was dumped in poorly managed landfills and dumpsites over the past decades and is an environmental and health hazard. Landfill mining is a promising solution to reclaim these sites along with the recovery of resources (materials and energy). During landfill mining operations, the combustible fraction is one of the major components recovered and needs proper management for maximizing resource recovery. For the identification of appropriate resource recovery options, knowledge of the physicochemical characteristics is required. The present study aims to assess the depth-wise change in the composition of legacy waste and the physicochemical characteristics of the combustible fraction. Furthermore, a material flow analysis considering the incineration of combustible fraction was performed to estimate the energy generation potential and the associated greenhouse gas (GHG) emissions. The results of the compositional analysis of dry legacy waste revealed that the fine fraction (<4 mm soil-like material) was dominating with a share of 36%. The depth-wise analysis showed a decrease in the calorific value with increasing landfill depth, while no specific trend was observed for the other parameters analyzed, including proximate and ultimate analysis, and chlorine content. The material flow analysis performed for 100 tonnes of wet legacy waste indicated that 52 tonnes of waste is combustible fraction. The GHG emissions through incineration of one tonne of dry combustible fraction would be 1389 kg CO2-eq, with 1125 kWh of electrical energy generation potential.


Assuntos
Gases de Efeito Estufa , Incineração , Instalações de Eliminação de Resíduos , Gases de Efeito Estufa/análise , Índia , Resíduos Sólidos/análise , Eliminação de Resíduos/métodos , Poluentes Atmosféricos/análise , Monitoramento Ambiental/métodos
5.
J Environ Manage ; 351: 119660, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38043310

RESUMO

Meta-analysis of red mud-related literature in English published from 1976 to 2022 and in Chinese from 1990 to 2022 was performed to support critical analysis and evaluation of the available literature based on the following aspects of red mud research: (a) characterization, (b) treatment for harmfulness minimization, (c) recovery of valuable metals, (d) environmental applications, and (e) uses as construction materials. It was found that (a) sinter red mud tended to contain more silica and calcium, and less iron, sodium and aluminium compared to Bayer red mud; (b) gypsum was the most frequently used agent for harmfulness reduction treatment of red mud, followed by flue gas/CO2; (c) the mean optimal pH for adsorption of major anionic pollutants was 8.42 ± 1.13 (arsenite), 3.73 ± 0.68 (arsenate), 3.50 ± 2.38 (phosphate), 4.43 ± 1.04 (fluoride) and 3.80 ± 1.54 (chromate); (d) wastewater treatment has attracted more attention compared to contaminated soils and waste gases; (e) recovery of iron and scandium has attracted more attention compared to other metals; (f) cement making has been the focus in construction uses. Most of the research findings were based on laboratory-scale experiments that focused on efficacy rather than efficiency. There was a lack of integrated approaches for research in red mud valorization.


Assuntos
Óxido de Alumínio , Poluição Ambiental , Óxido de Alumínio/química , Metais , Ferro , Alumínio
6.
J Environ Manage ; 356: 120622, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38513580

RESUMO

Insect farming has gained popularity as a resource-efficient and eco-friendly method for managing organic wastes by converting them into high-quality protein, fat, and frass. Insect frass is a powerful organic fertilizer that enriches the soil with essential plant nutrients and enhances plant defense mechanisms through chitin stimulation. Given the importance of frass commercialization for many insect farmers and the use of increasingly diverse organic wastes as insect feedstocks, there is a need for legal guidelines to enable clean production practices. The recent introduction of a legal definition for frass and heat treatment requirements by the EU commission marks a significant step towards standardizing its quality; however, little is known about the processes shaping its nutritional profiles and contributing to its maturation. Our study addresses key knowledge gaps in frass composition and production practices. Here, we analyzed the physicochemical, plant-nutritional, and microbiological properties of black soldier fly, yellow mealworm, and Jamaican field cricket frass from mass-rearing operations and assessed the impact of hygienizing heat treatment on fertilizer properties and frass microbiota. The results showed that frass properties varied significantly across insect species, revealing concentrations of plant-available nutrients as high as 7000 µg NH4+-N, 150 µg NO2-NO3--N, and 20 mg available P per g of total solids. Heat treatment reduced microbial activity, biomass, and viable counts of pathogenic Escherichia coli and Salmonella spp. In terms of frass microbiome composition, alpha diversity showed no significant differences between fresh and heat-treated frass samples; however, significant differences in microbial community composition were observed across the three insect species. Despite heat treatment, soil application of frass reactivated and boosted soil microbial activity, inducing up to a 25-fold increase in microbial respiration, suggesting no long-term detrimental effects on microorganisms. These findings not only enhance our understanding of insect frass as a nutrient-rich organic fertilizer but also have implications for regulatory frameworks, underscoring its promising potential for soil health and nutrient cycling. However, it is important to recognize the primary nature of this research, conducted at laboratory scale and over a short term. Future studies should aim to validate these findings in agricultural settings and explore additional factors influencing frass properties and its (long-term) interaction with soil ecosystems.


Assuntos
Fertilizantes , Solo , Animais , Solo/química , Fertilizantes/análise , Ecossistema , Temperatura Alta , Insetos
7.
J Environ Manage ; 356: 120580, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38518500

RESUMO

The burgeoning interest in resource recovery from old dumpsites has significantly propelled the adoption of Landfill Mining (LFM) in recent years. This study is centred around evaluating the quality of materials recovered from the full-scale LFM activities at two major dumpsites in India, focusing on the valorization potential of the segregated legacy waste. A detailed analysis was conducted on the segregated waste fractions based on particle size (-30 mm, 30 to 6 mm, and -6 mm, as sourced from the sites), employing both batch and column leaching methods across a range of liquid-to-solid (L/S) ratios (0.1-10.0 L/kg). The findings reveal a pronounced concentration of contaminants within the -6 mm fraction compared to the 30 to 6 mm and -30 mm fractions. Column leaching tests revealed a reduction in contaminant concentration, correlating with incremental changes in L/S ratio. Notably, this trend remained consistent across varying particle sizes and specific type of contaminants assessed. Notably, color intensity of leachate reduced significantly from 720 to 1640 Platinum Cobalt Units (PCU) at an L/S ratio of 0.1 L/kg to a minimal 94-225 PCU at an L/S of 10 L/kg. Dissolved salts emerged as a primary concern, marking them as significant contaminants in both leaching methods. The analysis confirmed that the segregated fractions comply with the USEPA Waste Acceptance Criteria (WAC), permitting their disposal in non-hazardous waste landfills. However, the elevated presence of dissolved salts, exceeding reuse limits by 5-35 times, limits their open or unrestricted reuse. Despite this, isolated reuse aligns with regulations from the Netherlands and Germany, suggesting viable pathways for compliant utilization. Geotechnical assessments indicate the potential for repurposing the -30 mm fraction as alternative earthfill and construction material. While heavy metal leaching does not pose significant concerns, the prevalent unscientific disposal practices near urban settlements highlight potential human health risks. This investigation enriches the understanding of the physicochemical properties, leaching behaviour, and reuse potential of segregated legacy waste, offering crucial insights for civic authorities in determining appropriate reuse and disposal strategies for such materials.


Assuntos
Metais Pesados , Eliminação de Resíduos , Humanos , Eliminação de Resíduos/métodos , Sais , Instalações de Eliminação de Resíduos , Metais Pesados/análise , Cobalto/análise , Resíduos Sólidos/análise
8.
Molecules ; 29(15)2024 Jul 27.
Artigo em Inglês | MEDLINE | ID: mdl-39124946

RESUMO

The high silicon content in rice plant waste, specifically rice husks, makes this waste by-product attractive for the extraction and valorization of silicon oxide, which is widely used as an inert support in catalysis, drug delivery and molecular sieving. The procedures currently used for the treatment of plant biomass make extensive use of mineral acids (HCl, H2SO4, HNO3), which, besides them being potential environmental pollutants, reduce the yield and worsen the chemical-physical properties of the product. In this study, an evaluation of the easy treatment of rice husks by benchmarking different, more eco-friendly carboxylic acids in order to obtain a mesoporous SiO2 with an alveolar structure and a relatively high surface area and pore volume (300-420 m2/g, 0.37-0.46 cm3/g) is presented. The obtained mesoporous silicas are characterized by worm-like pores with a narrow size distribution and a maximum in the range of 3.4-3.5 nm. The mesoporous structure of the obtained materials was also confirmed by TEM. The complete removal of the organic part of the rice husks in the final materials was evidenced by thermogravimetric analysis. The high purity of the obtained mesoporous silica was detected using ICP analysis (98.8 wt. %). The structure peculiarities of the obtained mesoporous silicas were also characterized by solid-state NMR and ATR-FTIR spectroscopies. The morphology of the mesoporous silica was investigated by SEM.


Assuntos
Oryza , Dióxido de Silício , Oryza/química , Dióxido de Silício/química , Porosidade , Espectroscopia de Infravermelho com Transformada de Fourier , Termogravimetria
9.
Molecules ; 29(7)2024 Apr 02.
Artigo em Inglês | MEDLINE | ID: mdl-38611868

RESUMO

Citrus fruits are one of the most widely used fruits around the world and are used as raw fruits, but are also processed into products such as beverages, and large amounts of by-products and waste are generated in this process. Globally, disposal of citrus waste (CW) through simple landfilling or ocean dumping can result in soil and groundwater contamination, which can negatively impact ecosystem health. The case of Korea is not much different in that these wastes are simply buried or recycled wastes are used as livestock feed additives. However, there are many reports that CW, which is a waste, has high potential to produce a variety of products that can minimize environmental load and increase added value through appropriate waste management. In this study, we aim to explore the latest developments in the evaluation and valorization of the growing CW green technologies in an effort to efficiently and environmentally transform these CW for resource recovery, sustainability, and economic benefits. Recent research strategies on integrated biorefinery approaches have confirmed that CW can be converted into various bioproducts such as enzymes, biofuels and biopolymers, further contributing to energy security. It was found that more efforts are needed to scale up green recovery technologies and achieve diverse product profiling to achieve zero waste levels and industrial viability.


Assuntos
Citrus , Gerenciamento de Resíduos , Ecossistema , Estudos de Viabilidade , República da Coreia
10.
Molecules ; 29(16)2024 Aug 11.
Artigo em Inglês | MEDLINE | ID: mdl-39202895

RESUMO

This study focuses on investigating sugar recovery from spoiled date fruits (SDF) for sustainable ethanol production using newly isolated yeasts. Upon their isolation from different food products, yeast strains were identified through PCR amplification of the D1/D2 region and subsequent comparison with the GenBank database, confirming isolates KKU30, KKU32, and KKU33 as Saccharomyces cerevisiae; KKU21 as Zygosaccharomyces rouxii; and KKU35m as Meyerozyma guilliermondii. Optimization of sugar extraction from SDF pulp employed response surface methodology (RSM), varying solid loading (20-40%), temperature (20-40 °C), and extraction time (10-30 min). Linear models for sugar concentration (R1) and extraction efficiency (R2) showed relatively high R2 values, indicating a good model fit. Statistical analysis revealed significant effects of temperature and extraction time on extraction efficiency. The results of batch ethanol production from SDF extracts using mono-cultures indicated varying consumption rates of sugars, biomass production, and ethanol yields among strains. Notably, S. cerevisiae strains exhibited rapid sugar consumption and high ethanol productivity, outperforming Z. rouxii and M. guilliermondii, and they were selected for scaling up the process at fed-batch mode in a co-culture. Co-cultivation resulted in complete sugar consumption and higher ethanol yields compared to mono-cultures, whereas the ethanol titer reached 46.8 ± 0.2 g/L.


Assuntos
Etanol , Etanol/metabolismo , Phoeniceae/metabolismo , Phoeniceae/química , Frutas/química , Frutas/metabolismo , Saccharomyces cerevisiae/metabolismo , Saccharomyces cerevisiae/genética , Açúcares/metabolismo , Açúcares/análise , Fermentação , Leveduras/metabolismo , Leveduras/genética , Leveduras/isolamento & purificação
11.
Artigo em Inglês | MEDLINE | ID: mdl-38884568

RESUMO

Water treatment plants (WTPs) produce thousands of tons of sludge annually, which is destined for landfill disposal, an environmentally and economically impractical alternative. Chemical, mineralogical, and morphological characterization besides environmental classification has been performed for WTP sludge and it was evaluated application potential in building materials, from a literature review. The characterization was carried out by X-ray fluorescence spectrometry, X-ray diffraction, scanning electron microscopy analysis, and leaching and solubilization tests. The results show that the presence of activated charcoal residues from water treatment in one type of sludge was of little relevance for changes in the properties of the waste. Both sludges have a wide range of particle sizes, consisting mainly of silica, aluminum and iron oxides, as well as kaolinite, quartz, and iron minerals. Special attention must be paid to the solubilization of metallic contaminants to avoid contamination risks and order to make the application safer and more effective, it is necessary to study deeply ways to inert the WTP sludge. The sludges studied have a high potential for application in ceramic products, mortars, geopolymers and concrete paving stones. Depending on the type of building material, different contents of sludge in natural or calcined state can be incorporated.


Assuntos
Materiais de Construção , Esgotos , Materiais de Construção/análise , Esgotos/química , Purificação da Água/métodos , Reciclagem/métodos , Difração de Raios X , Microscopia Eletrônica de Varredura , Espectrometria por Raios X , Eliminação de Resíduos Líquidos/métodos
12.
J Environ Sci (China) ; 140: 69-78, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38331516

RESUMO

Herein we study the economic performance of hydrochar and synthetic natural gas co-production from olive tree pruning. The process entails a combination of hydrothermal carbonization and methanation. In a previous work, we evidenced that standalone hydrochar production via HTC results unprofitable. Hence, we propose a step forward on the process design by implementing a methanation, adding value to the gas effluent in an attempt to boost the overall process techno-economic aspects. Three different plant capacities were analyzed (312.5, 625 and 1250 kg/hr). The baseline scenarios showed that, under the current circumstances, our circular economy strategy in unprofitable. An analysis of the revenues shows that hydrochar selling price have a high impact on NPV and subsidies for renewable coal production could help to boost the profitability of the process. On the contrary, the analysis for natural gas prices reveals that prices 8 times higher than the current ones in Spain must be achieved to reach profitability. This seems unlikely even under the presence of a strong subsidy scheme. The costs analysis suggests that a remarkable electricity cost reduction or electricity consumption of the HTC stage could be a potential strategy to reach profitability scenarios. Furthermore, significant reduction of green hydrogen production costs is deemed instrumental to improve the economic performance of the process. These results show the formidable techno-economic challenge that our society faces in the path towards circular economy societies.


Assuntos
Carbono , Gás Natural , Temperatura
13.
Waste Manag Res ; : 734242X241273800, 2024 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-39279233

RESUMO

This study evaluates the use of carbon-encapsulated zero-valent iron nanoparticles for biogas upgrading in wet systems. The nanoparticles were produced by hydrothermal carbonization, using olive mill waste (OMW) or microalgae as carbon sources. The solids were characterized to investigate the specific surface area, total and zero-valent iron content, pHPZC and chemical and crystalline composition. Their adsorption performance towards hydrogen sulphide (H2S) was tested by treating two types of synthetic biogas with and without CO2. In both cases, the starting H2S concentration was approximately 60 ppm and the experiments lasted until the complete saturation of the nanoparticles. Optimal Fe/C ratios of 0.05 for OMW nanoparticles and 0.2 for microalgae nanoparticles demonstrated H2S-specific adsorption capacities of 9.66 and 9.55 mgH2SgCE-nZVI-1, respectively, in a synthetic biogas without CO2. The addition of CO2 in biogas reduced adsorption, possibly due to system acidification. X-ray photoelectron spectroscopy analysis revealed surface compounds on the surface of the spent nanoparticles, including disulphides, polysulphides and sulphate. The saturated adsorbents were effectively regenerated with air, leading to the oxidation of sulphur species and desorption. The regeneration allowed a total adsorption capacity of 53.25 and 34.14 mgH2SgCE-nZVI-1, after 10 consecutive cycles of adsorption/regeneration with a single batch of olive mill and microalgae nanoparticles, respectively.

14.
Waste Manag Res ; 42(3): 260-272, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-37382414

RESUMO

With global municipal solid waste generation increasing steadily, the importance of high-quality, environmentally friendly waste valorization methods is rising, too. Most countries have set themselves ambitious recycling goals and follow a waste hierarchy in which recycling is more preferable than energy recovery. This article focuses on a waste treatment option that already is an integral part of waste management in some countries and enables the simultaneous recovery of energy and mineral constituents: the production of solid recovered fuels (SRFs) from mixed municipal and commercial waste and their use in the cement industry is often referred to as co-processing. The state of the art of SRF production is described and the first comprehensive dataset for SRF samples including major constituents, heavy metal and metalloid contents, energy- and CO2-emission-relevant parameters, ash constituents and the material-recyclable share of SRF is presented. Additionally, a comparison with fossil fuels is given. It is concluded that SRF from state-of-the-art production plants complies with strict limit values for heavy metals, has an average biogenic carbon content of 60%, and its application in the cement industry can be considered as partial recycling (14.5%) and partial energy recovery (85.5%). Leaving no residues to be dealt with, co-processing of waste in the cement industry therefore offers many benefits and can support the shift from a linear to a circular economy.


Assuntos
Carbono , Gerenciamento de Resíduos , Indústrias , Reciclagem , Resíduos Sólidos
15.
J Food Sci Technol ; 61(8): 1536-1546, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38966785

RESUMO

Pearl millet bran is rich source of dietary fiber and several other bioactive compounds and is an unexploited by-product of millet processing industries. The utilization of pearl millet bran for extraction of dietary fiber can be an effective method for its valorization. Hydrothermal extraction of dietary fiber from pearl millet bran is a simple eco-friendly technique in terms of minimal consumption of toxic solvents, increased extraction yield, high purity and considered as an economically viable technique. In the present investigation, extraction and optimization of dietary fiber from pearl millet bran was performed using hydrothermal technique. The highest yield of dietary fiber (74.5%, w/w) was obtained under optimized conditions of water to solid ratio (20:1), temperature (90 °C) and time (15 min). The extracted dietary fiber from pearl millet bran was further assessed for its physico-chemical, functional and structural properties. The studies of functional and physico-chemical properties presented the water holding capacity (6.50 g/g and 3.99 g/g), swelling power (2.0 g/g and 2.05 g/g), oil holding capacity (4.91 g/g and 2.42 g/g), solubility (70%), total phenolic content of 4.24 mg GAE/g and 4.32 mg GAE/g, DPPH reduction of 86.6% and 83.9%, respectively. The results indicated that pearl millet bran can act as rich source of dietary fiber with health enhancing properties and can be utilized as potential food component in preparation of functional food products.

16.
Angew Chem Int Ed Engl ; : e202416384, 2024 Oct 07.
Artigo em Inglês | MEDLINE | ID: mdl-39373567

RESUMO

We demonstrate a novel approach of utilizing methanol (CH3OH) in a dual role for (1) the methanolysis of polyethylene terephthalate (PET) to form dimethyl terephthalate (DMT) at near-quantitative yields (~97%) and (2) serving as an in-situ H2 source for the catalytic transfer hydrogenolysis (CTH) of DMT to p-xylene (PX, ~63% at 240 °C and 16 h) on a reducible ZnZrOx supported Cu catalyst (i.e., Cu/ZnZrOx). Pre- and post-reaction surface and bulk characterization, along with density functional theory (DFT) computations, explicate the dual role of the metal-support interface of Cu/ZnZrOx in activating both CH3OH and DMT and facilitating a lower free-energy pathway for both CH3OH dehydrogenation and DMT hydrogenolysis, compared to Cu supported on a redox-neutral SiO2 support. Loading studies and thermodynamic calculations showed that, under reaction conditions, CH3OH in the gas phase, rather than in the liquid phase, is critical for CTH of DMT. Interestingly, the Cu/ZnZrOx catalyst was also effective for the methanolysis and hydrogenolysis of C-C bonds (compared to C-O bonds for PET) of waste polycarbonate (PC), largely forming xylenol (~38%) and methyl isopropyl anisole (~42%) demonstrating the versatility of this approach toward valorizing a wide range of condensation polymers.

17.
Crit Rev Biotechnol ; : 1-19, 2023 Sep 24.
Artigo em Inglês | MEDLINE | ID: mdl-37743323

RESUMO

Owing to the increasing worldwide population explosion, managing waste generated from the food sector has become a cross-cutting issue globally, leading to environmental, economic, and social issues. Circular economy-inspired waste valorization approaches have been increasing steadily, generating new business opportunities developing valuable bioproducts using food waste, especially fruit wastes, that may have several applications in energy-food-pharma sectors. Dragon fruit waste is one such waste resource, which is rich in several value-added chemicals and oils, and can be a renewable resource to produce several value-added compounds of potential applications in different industries. Pretreatment and extraction processes in biorefineries are important strategies for recovering value-added biomolecules. There are different methods of valorization, including green extractions and biological conversion approaches. However, microbe-based conversion is one of the advanced technologies for valorizing dragon fruit waste into bioethanol, bioactive products, pharmaceuticals, and other valued products by reusing or recycling them. This state-of-the-art review briefly overviews the dragon fruit waste management strategies and advanced eco-friendly and cost-effective valorization technologies. Furthermore, various applications of different valuable bioactive components obtained from dragon fruit waste have been critically discussed concerning various industrial sectors. Several industrial sectors, such as food, pharmaceuticals, and biofuels, have been critically reviewed in detail.

18.
Crit Rev Food Sci Nutr ; : 1-19, 2023 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-36876476

RESUMO

Worldwide, many production supply chains generate a considerable amount of legume by-products (e.g., leaves, husks, broken seeds, defatted cakes). These wastes can be revalorized to develop sustainable protein ingredients, with positive economic and environmental effects. To separate protein from legume by-products, a broad spectrum of conventional (e.g., alkaline solubilization, isoelectric precipitation, membrane filtration) and novel methodologies (e.g., ultrasound, high-pressure homogenization, enzymatic approaches) have been studied. In this review, these techniques and their efficiency are discussed in detail. The present paper also provides an overview of the nutritional and functional characteristics of proteins extracted from legume by-products. Moreover, existing challenges and limitations associated with the valorization of by-product proteins are highlighted, and future perspectives are proposed.

19.
Crit Rev Food Sci Nutr ; 63(6): 719-752, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-34309440

RESUMO

Fruits and vegetables are the most important commodities of trade value among horticultural produce. They are utilized as raw or processed, owing to the presence of health-promoting components. Significant quantities of waste are produced during fruits and vegetables processing that are majorly accounted by waste peels (∼90-92%). These wastes, however, are usually exceptionally abundant in bioactive molecules. Retrieving these valuable compounds is a core objective for the valorization of waste peel, besides making them a prevailing source of beneficial additives in food and pharmaceutical industry. The current review is focused on extraction of bioactive compounds derived from fruit and vegetable waste peels and highlights the supreme attractive conventional and non-conventional extraction techniques, such as microwave-assisted, ultrasound assisted, pulsed electric fields, pulsed ohmic heating, pressurized liquid extraction, supercritical fluid extraction, pressurized hot water, high hydrostatic pressure, dielectric barrier discharge plasma extraction, enzyme-assisted extraction and the application of "green" solvents say as well as their synergistic effects that have been applied to recover bioactive from waste peels. Superior yields achieved with non-conventional technologies were identified to be of chief interest, considering direct positive economic consequences. This review also emphasizes leveraging efficient, modern extraction technologies for valorizing abundantly available low-cost waste peel, to achieve economical substitutes, whilst safeguarding the environment and building a circular economy. It is supposed that the findings discussed though this review might be a valuable tool for fruit and vegetable processing industry to imply an economical and effectual sustainable extraction methods, converting waste peel by-product to a high added value functional product.


Assuntos
Frutas , Verduras , Frutas/química , Antioxidantes/análise , Solventes
20.
Crit Rev Food Sci Nutr ; 63(23): 6330-6343, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-35089825

RESUMO

The excellent health benefits of oil extracted from seeds have increased its application in foods, pharmaceutical and cosmetic industries. This trend leads to a growing research area on their by-products, oilseed meals, to minimize environmental and economic issues. Examples of these by-products are soybean, peanut, kenaf seed, hemp, sesame, and chia seed meals. It is well known that soybean meals have wide applications in food and non-food industries, while other seed meals are not well established. Most oilseed meals are rich in health beneficial compounds and are potential sources of plant protein, dietary fiber, and antioxidants. Many studies have reported on the valorization of these by-products into value-added food products such as bakery and meat products to increase their nutritional and functional properties. These efforts contribute to the sustainability, development of novel functional food and support the zero-waste concept for the environment. This review aims to provide information on the composition of selected oilseed meals from soybean, peanut, hemp, kenaf, sesame and chia seeds, their potential applications in the bakery, meat, beverage, pasta, and other food products, and to highlight the issues and challenges associated with the utilization of oilseed meals into various food products.


Assuntos
Antioxidantes , Extratos Vegetais , Sementes , Refeições
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