Production of O2 Herzberg states in the deep UV photodissociation of ozone.
J Chem Phys
; 131(1): 011101, 2009 Jul 07.
Article
en En
| MEDLINE
| ID: mdl-19586089
ABSTRACT
High-resolution imaging experiments combined with new electronic structure and dynamics calculations strongly indicate that the O((3)P)+O(2) products with very low kinetic energy release (E(tr)<0.2 eV) formed in the deep UV (226 nm) photodissociation of ozone reflect excitation of the Herzberg states of O(2) A(')(3)Delta(u)(v=0,1,2) and A (3)Sigma(u)(+)(v=0,1). This interpretation contradicts the earlier assignment to very high (v> or =26) vibrational states of O(2)((3)Sigma(g)(-)).
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Chem Phys
Año:
2009
Tipo del documento:
Article
País de afiliación:
Alemania