Mesoporous spherical Li4Ti5O12 as high-performance anodes for lithium-ion batteries.
Chem Asian J
; 9(9): 2514-8, 2014 Sep.
Article
en En
| MEDLINE
| ID: mdl-24909929
ABSTRACT
Porous microspherical Li4Ti5O12 aggregates (LTO-PSA) can be successfully prepared by using porous spherical TiO2 as a titanium source and lithium acetate as a lithium source followed by calcinations. The synthesized LTO-PSA possess outstanding morphology, with nanosized, porous, and spherical distributions, that allow good electrochemical performances, including high reversible capacity, good cycling stability, and impressive rate capacity, to be achieved. The specific capacity of the LTO-PSA at 30â
C is as high as 141â
mA h g(-1), whereas that of normal Li4Ti5O12 powders prepared by a sol-gel method can only achieve 100â
mA h g(-1). This improved rate performance can be ascribed to small Li4Ti5O12 nanocrystallites, a three-dimensional mesoporous structure, and enhanced ionic conductivity.
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01-internacional
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MEDLINE
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En
Revista:
Chem Asian J
Año:
2014
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Article