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Synthesis of Perfluorinated Isoquinolinediones through Visible-Light-Induced Cyclization of Alkenes.
Tang, Shi; Deng, You-Lin; Li, Jie; Wang, Wen-Xin; Ding, Guo-Liang; Wang, Ming-Wei; Xiao, Zhu-Ping; Wang, Ying-Chun; Sheng, Rui-Long.
Afiliación
  • Tang S; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Deng YL; College of Chemistry and Chemical Engineering, Central South University , Changsha 410083, China.
  • Li J; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Wang WX; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Ding GL; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Wang MW; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Xiao ZP; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Wang YC; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
  • Sheng RL; College of Chemistry and Chemical Engineering, Jishou University , Jishou 416000, China.
J Org Chem ; 80(24): 12599-605, 2015 Dec 18.
Article en En | MEDLINE | ID: mdl-26580021
A novel visible-light-induced carboperfluoroalkylation of alkenes using perfluoroalkyl iodides and bromides as Rf sources, leading to isoquinoline-1,3-diones, was developed. This method offers rapid entry to perfluorinated isoquinoline-1,3(2H,4H)-diones from N-alkyl-N-methacryloyl benzamides under mild reaction conditions, allowing for the incorporation of a wide variety of perfluorinated groups such as CF3, C3F7, C4F9, C6F13, C8F17, C10F21, and CF2CO2Et.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2015 Tipo del documento: Article País de afiliación: China
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2015 Tipo del documento: Article País de afiliación: China