A Photocatalyzed Cascade Approach Toward the Tetracyclic Core of Akuammiline Alkaloids.
Org Lett
; 21(3): 614-617, 2019 02 01.
Article
en En
| MEDLINE
| ID: mdl-30638388
ABSTRACT
A cascade approach toward the tetracyclic core of akuammiline alkaloids which features high modularity and convergence is reported. Distinct substitution pattern can be readily introduced to the tetracyclic core by varying three building blocks with similar complexity. The critical event in the cascade is a regio- and stereoselective 1,2-shift enabled by a carbocation that sets up the core.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2019
Tipo del documento:
Article
País de afiliación:
Estados Unidos