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Controlled Assembly Synthesis of Atomically Precise Ultrastable Silver Nanoclusters with Polyoxometalates.
Yonesato, Kentaro; Ito, Hiroyasu; Itakura, Hiroyuki; Yokogawa, Daisuke; Kikuchi, Takashi; Mizuno, Noritaka; Yamaguchi, Kazuya; Suzuki, Kosuke.
Afiliación
  • Yonesato K; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
  • Ito H; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
  • Itakura H; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
  • Yokogawa D; Graduate School of Arts and Science , The University of Tokyo , 3-8-1 Komaba , Meguro-ku, Tokyo 153-8902 , Japan.
  • Kikuchi T; Rigaku Corporation , 3-9-12 Matsubaracho , Akishima, Tokyo 196-8666 , Japan.
  • Mizuno N; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
  • Yamaguchi K; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
  • Suzuki K; Department of Applied Chemistry, School of Engineering , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-8656 , Japan.
J Am Chem Soc ; 141(50): 19550-19554, 2019 Dec 18.
Article en En | MEDLINE | ID: mdl-31800238
ABSTRACT
Silver nanoclusters have attracted scientific interest due to their properties and applications. However, practical synthetic methods to access these materials are still limited mainly due to the low stability. Here, we report a controlled assembly strategy for fabricating atomically precise silver nanoclusters using polyoxometalates (POMs) as structure-directing as well as functionalizing units. A trefoil-propeller-shaped {Ag27}17+ nanocluster was synthesized by assembling reactive nanoclusters supported by open-Dawson-type POMs [Si2W18O66]16-. The {Ag27}17+ nanocluster possessed 10 delocalized valence electrons and showed unprecedented ultrastability in solutions. The cluster showed unique {Ag27}-to-POM charge transfer bands in the visible light region.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Japón