Electric Field Enhances Shear Resistance of Polymer Melts via Orientational Polarization in Microstructures.
Polymers (Basel)
; 12(2)2020 Feb 05.
Article
en En
| MEDLINE
| ID: mdl-32033328
ABSTRACT
In this paper, we studied the alteration of viscoelastic properties of a neat poly(methyl methacrylate) (PMMA), induced by an applied external electric field. The rheological properties of PMMA are measured using a rotational rheometer at elevated temperatures. The electric field effect on the shear resistance of the polymer was studied by examining rheological responses under difference experimental scenarios. We find that the external electric field can remarkably enhance shear resistance and prevent flow of PMMA melt, enabling it to behave more predictably at high temperatures. Dynamic rheological analysis illustrates that the external electric field speeds up the recovery of mechanical properties of the PMMA melt after large deformations, whereas the PMMA melt exhibits thixotropic behaviors. The recovery velocity is influenced by the strength of the electric field, specifically, and is found to be proportional to the electric field strength. Our experimental characterization may provide new evidence on the tuning mechanical properties of polymer melts via controlling segmental polarization.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Polymers (Basel)
Año:
2020
Tipo del documento:
Article
País de afiliación:
China