Direct observation of t2g orbital ordering in magnetite.
Phys Rev Lett
; 100(2): 026406, 2008 Jan 18.
Article
em En
| MEDLINE
| ID: mdl-18232896
ABSTRACT
Using soft-x-ray diffraction at the site-specific resonances in the Fe L2,3 edge, we find clear evidence for orbital and charge ordering in magnetite below the Verwey transition. The spectra show directly that the (001/2) diffraction peak (in cubic notation) is caused by t2g orbital ordering at octahedral Fe2+ sites and the (001) by a spatial modulation of the t2g occupation.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Ano de publicação:
2008
Tipo de documento:
Article
País de afiliação:
Alemanha