Proton-fueled DNA-duplex-based stimuli-responsive reversible assembly of single-walled carbon nanotubes.

ABSTRACT

Single-walled carbon nanotubes (SWNTs) have received much attention in nanotechnology because of their potential applications in molecular electronics, field-emission devices, biomedical engineering, and biosensors. Carbon nanotubes as gene and drug delivery vectors or as "building blocks" in nano-/microelectronic devices has been successfully explored. However, since SWNTs lack chemical recognition, SWNT-based electronic devices and sensors are strictly related to the development of a bottom-up self-assembly technique. Here we present an example of using DNA duplex-based protons (H(+)) as a fuel to control reversible assembly of SWNTs without generation of waste duplex products that poison DNA-based systems.