Synthesis of enantiopure P-stereogenic diphosphacrowns using P-stereogenic secondary phosphines.
J Org Chem
; 78(6): 2769-74, 2013 Mar 15.
Article
em En
| MEDLINE
| ID: mdl-23402378
ABSTRACT
A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Japão