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(±)-(4aR,5R,8S,8aR)-8-(tert-Butyl-dimethyl-sil-yloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetra-hydro-naphthalene-1,4-dione.
Delling, Felix N; Zukerman-Schpector, Julio; Brocksom, Timothy J; Brocksom, Ursula; Finelli, Fernanda G; Tiekink, Edward R T.
Afiliação
  • Delling FN; Department of Chemistry, Universidade Federal de São Carlos, 13565-905 São Carlos, SP, Brazil.
Acta Crystallogr Sect E Struct Rep Online ; 69(Pt 3): o325, 2013 Mar 01.
Article em En | MEDLINE | ID: mdl-23476523
ABSTRACT
In the title compound, C19H30O3Si, both rings adopt a half-boat conformation. Overall, the mol-ecule approximates a U-shape as the cyclo-2-ene-1,4-dione and butyl-dimethyl-sil-yloxy substituents lie to the same side of the central cyclo-hexene ring; the methyl substituent lies to the other side of the mol-ecule. In the crystal, linear supra-molecular chains along the b axis are sustained by C-H⋯O inter-actions.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2013 Tipo de documento: Article País de afiliação: Brasil

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Ano de publicação: 2013 Tipo de documento: Article País de afiliação: Brasil