Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex.
J Am Chem Soc
; 140(50): 17369-17373, 2018 12 19.
Article
em En
| MEDLINE
| ID: mdl-30500184
ABSTRACT
Reduction of IU(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U(II) complex, U(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f46d0 valence electronic configuration for uranium, along with characterization of related U(III) complexes.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Urânio
/
Complexos de Coordenação
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Estados Unidos