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Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex.
Billow, Brennan S; Livesay, Brooke N; Mokhtarzadeh, Charles C; McCracken, John; Shores, Matthew P; Boncella, James M; Odom, Aaron L.
Afiliação
  • Billow BS; Department of Chemistry . Michigan State University , 578 S. Shaw Lane , East Lansing , Michigan 48824 , United States.
  • Livesay BN; Department of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.
  • Mokhtarzadeh CC; Chemistry Division , Los Alamos National Laboratory , Los Alamos , New Mexico 87545 , United States.
  • McCracken J; Department of Chemistry . Michigan State University , 578 S. Shaw Lane , East Lansing , Michigan 48824 , United States.
  • Shores MP; Department of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.
  • Boncella JM; Chemistry Division , Los Alamos National Laboratory , Los Alamos , New Mexico 87545 , United States.
  • Odom AL; Department of Chemistry . Michigan State University , 578 S. Shaw Lane , East Lansing , Michigan 48824 , United States.
J Am Chem Soc ; 140(50): 17369-17373, 2018 12 19.
Article em En | MEDLINE | ID: mdl-30500184
ABSTRACT
Reduction of IU(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U(II) complex, U(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f46d0 valence electronic configuration for uranium, along with characterization of related U(III) complexes.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Urânio / Complexos de Coordenação Idioma: En Revista: J Am Chem Soc Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Urânio / Complexos de Coordenação Idioma: En Revista: J Am Chem Soc Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos