Organoboron Derivatives of Stereoregular Phenylcyclosilsesquioxanes.

Anisimov, Anton A; Drozdov, Fedor V; Vysochinskaya, Yulia S; Minyaylo, Ekaterina O; Peregudov, Alexander S; Dolgushin, Fedor M; Shchegolikhina, Olga I; Muzafarov, Aziz M

Anisimov, Anton A; Drozdov, Fedor V; Vysochinskaya, Yulia S; Minyaylo, Ekaterina O; Peregudov, Alexander S; Dolgushin, Fedor M; Shchegolikhina, Olga I; Muzafarov, Aziz M.

Afiliação

Anisimov AA; A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilova St. 28, Moscow, Russia.
Drozdov FV; Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences (ISPM RAS), Moscow, Russia.
Vysochinskaya YS; A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilova St. 28, Moscow, Russia.
Minyaylo EO; Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences (ISPM RAS), Moscow, Russia.
Peregudov AS; A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilova St. 28, Moscow, Russia.
Dolgushin FM; A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilova St. 28, Moscow, Russia.
Shchegolikhina OI; A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS), Vavilova St. 28, Moscow, Russia.
Muzafarov AM; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences (IGIC RAS), Moscow, Russia.

Chemistry ; 26(50): 11404-11407, 2020 Sep 04.

Article em En | MEDLINE | ID: mdl-32315105

ABSTRACT

ABSTRACT

This study presents the synthesis of organoboron derivatives of stereoregular 4-, 6-, and 12-unit phenylcyclosilsesquioxanes. All compounds obtained were isolated in good yields (70-80 %) and were fully characterized by 1 H, 13 C, 29 Si, 11 BâNMR, IR spectroscopy, HRMS ESI, and elemental microanalysis. The structure of the key modifier, obtained for the first time, 4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl) dimethylvinylsilane, was also confirmed by single-crystal XRD.

Palavras-chave

coordination chemistry; inorganic chemistry; methodology and reactions; organoboron derivatives; organocyclosilsesquioxanes

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Federação Russa

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