Energetic Metal-Organic Frameworks Derived Highly Nitrogen-Doped Porous Carbon for Superior Potassium Storage.
Small
; 16(43): e2002771, 2020 Oct.
Article
em En
| MEDLINE
| ID: mdl-33015902
ABSTRACT
The carbonaceous materials with low cost and high safety have been considered as promising anodes for potassium-ion batteries (PIBs). However, it is still a challenge to design a carbonaceous material with long cycle life and high rate performance due to the poor K+ reaction kinetics. Herein, this article reports a N-doped porous carbon framework (NPCF) with a high nitrogen content of 13.57 at% within high doping level of the pyrrolic N and pyridinic N, which exhibits a high reversible capacity of 327 mA h g-1 over 100 cycles at a current density of 100 mA g-1 , excellent rate capability (144 and 105 mA h g-1 at 10 and 20 A g-1 , respectively) and great cyclability of 258.9 mA h g-1 after 2000 cycles at 1 A g-1 . Such a high rate performance and excellent cycling stability anode material is seldom reported in PIBs. Density functional theory (DFT) calculations reveal that the pyrrolic and pyridinic N-doping are helpful to enhance the K adsorption ability, thereby increasing the specific capacity.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Small
Assunto da revista:
ENGENHARIA BIOMEDICA
Ano de publicação:
2020
Tipo de documento:
Article