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The Synthesis and Characterisation of a Molecular Sea-Serpent: Studies of a {Cr24 Cu7 } Chain.
Alotaibi, Rajeh; Fowler, Jonathan M; Lockyer, Selena J; Timco, Grigore A; Collison, David; Schnack, Jürgen; Winpenny, Richard E P.
Afiliação
  • Alotaibi R; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
  • Fowler JM; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
  • Lockyer SJ; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
  • Timco GA; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
  • Collison D; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
  • Schnack J; Faculty of Physics, Bielefeld University, P.O. box 100131, 33501, Bielefeld, Germany.
  • Winpenny REP; Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Angew Chem Int Ed Engl ; 60(17): 9489-9492, 2021 Apr 19.
Article em En | MEDLINE | ID: mdl-33576165
ABSTRACT
A finite chain of thirty-one paramagnetic centers is reported, synthesized by reaction of hydrated chromium fluoride, copper carbonate and pivalic acid in the presence of 1,4,7,10-tetrazacyclododecane (cyclen). Magnetic studies show predominantly anti-ferromagnetic exchange leading to a high density of low-lying spin states and large saturation field.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Reino Unido
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Reino Unido