Formation of Breslow Intermediates from N-Heterocyclic Carbenes and Aldehydes Involves Autocatalysis by the Breslow Intermediate, and a Hemiacetal.

Wessels, Alina; Klussmann, Martin; Breugst, Martin; Schlörer, Nils E; Berkessel, Albrecht

Wessels, Alina; Klussmann, Martin; Breugst, Martin; Schlörer, Nils E; Berkessel, Albrecht.

Afiliação

Wessels A; Department of Chemistry, Organic Chemistry, University of Cologne, Greinstraße 4, 50939, Cologne, Germany.
Klussmann M; Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platzâ1, 45470, Mülheim an der Ruhr, Germany.
Breugst M; Borchers GmbH, Berghausener Straße 100, 40764, Langenfeld, Germany.
Schlörer NE; Department of Chemistry, Organic Chemistry, University of Cologne, Greinstraße 4, 50939, Cologne, Germany.
Berkessel A; Department of Chemistry, Organic Chemistry, University of Cologne, Greinstraße 4, 50939, Cologne, Germany.

Angew Chem Int Ed Engl ; 61(23): e202117682, 2022 Jun 07.

Article em En | MEDLINE | ID: mdl-35238462

Palavras-chave

Autocatalysis; Breslow Intermediate; Carbenes; NMR; Reaction Mechanisms

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Alemanha

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